\(m_{Fe_2\left(SO_4\right)_3}=\dfrac{200\cdot20}{100}=40\left(g\right)\Rightarrow n=0,1mol\)

\(Fe_2\left(SO_4\right)_3+6NaOH\rightarrow2Fe\left(OH\right)_3\downarrow+3Na_2SO_4\)

0,1                    0,6              0,2                   0,3

a)\(m_{NaOH}=0,6\cdot40=24\left(g\right)\)

b)\(m_{Fe\left(OH\right)_3}=0,2\cdot107=21,4\left(g\right)\)

c)\(m_{Na_2SO_4}=0,3\cdot142=42,6\left(g\right)\)

   \(m_{ddsau}=200+24-21,4=202,6\left(g\right)\)

   \(\Rightarrow C\%=\dfrac{42,6}{202,6}\cdot100\%=21,03\%\)

\(n_{FeCl_3}=\dfrac{48,75}{162,5}=0,3(mol)\\ 3NaOH+FeCl_3\to Fe(OH)_3\downarrow+3NaCl\\ \Rightarrow n_{Fe(OH)_3}=0,3(mol);n_{NaOH}=n_{NaCl}=0,9(mol)\\ a,m_{Fe(OH)_3}=0,3.107=32,1(g)\\ b,m_{dd_{NaOH}}=\dfrac{0,9.40}{10\%}=360(g)\\ c,C\%_{NaCl}=\dfrac{0,9.58,5}{360+48,75-32,1}.100\%=13,98\%\\ \)

\(d,2Fe(OH)_3+3H_2SO_4\to Fe_2(SO_4)_3+6H_2O\\ \Rightarrow n_{H_2SO_4}=0,45(mol)\\ \Rightarrow m_{dd_{H_2SO_4}}=\dfrac{0,45.98}{20\%}=220,5(g)\\ \Rightarrow V_{dd_{H_2SO_4}}=\dfrac{220,5}{1,14}=193,42(ml)\)

a)\(n_{CuSO_4}=0,4.0,5=0,2\left(mol\right)\)

\(PTHH:CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\)

Mol:               0,2                0,4                   0,2

⇒ \(m_{Cu\left(OH\right)_2}=0,2.98=19,6\left(g\right)\)

b)\(C_{M\left(ddNaOH\right)}=\dfrac{0,4}{0,3}=1,3\left(M\right)\)

c)\(PTHH:Cu\left(OH\right)_2\underrightarrow{t^o}CuO+H_2O\)

Mol:                 0,2                   0,2

=> m_CuO = 0,2.80 = 16 (g)

\(n_{CuSO_4}=\dfrac{200.16\%}{160}=0,2\left(mol\right)\)

PTHH :

\(CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2\downarrow+Na_2SO_4\)

0,2              0,4                  0,2               0,2 

\(m_{NaOH}=0,4.40=16\left(g\right)\)

\(m_{ddNaOH}=\dfrac{16.100}{10}=160\left(g\right)\)

\(c,m_{Na_2SO_4}=0,2.142=28,4\left(g\right)\)

\(m_{ddNa_2SO_4}=200+160-\left(0,2.98\right)=340,4\left(g\right)\)

\(C\%_{Na_2SO_4}=\dfrac{28,4}{240,4}.100\%\approx8,34\%\)

\(d,PTHH:\)

\(Cu\left(OH\right)_2\underrightarrow{t^o}CuO+H_2O\)

0,2               0,2 

\(m_{CuO}=0,2.80=16\left(g\right)\)

a, \(CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\)

b, \(m_{CuSO_4}=200.16\%=32\left(g\right)\Rightarrow n_{CuSO_4}=\dfrac{32}{160}=0,2\left(mol\right)\)

\(n_{NaOH}=2n_{CuSO_4}=0,4\left(mol\right)\Rightarrow m_{ddNaOH}=\dfrac{0,4.40}{10\%}=160\left(g\right)\)

c, \(n_{Cu\left(OH\right)_2}=n_{Na_2SO_4}=n_{CuSO_4}=0,2\left(mol\right)\)

\(\Rightarrow C\%_{Na_2SO_4}=\dfrac{0,2.142}{200+160-0,2.98}.100\%\approx8,34\%\)

d, \(Cu\left(OH\right)_2\underrightarrow{t^o}CuO+H_2O\)

\(n_{CuO}=n_{Cu\left(OH\right)_2}=0,2\left(mol\right)\Rightarrow m_{CuO}=0,2.80=16\left(g\right)\)

\(n_{CuSO_4}=\dfrac{15,2}{160}=0,095mol\\ CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\)

0,095          0,19              0,095            0,095

\(m_{rắn}=m_{Cu\left(OH\right)_2}=0,095.98=9,31g\\ V_{ddNaOH}=\dfrac{0,19}{2}=0,095l\\ b)C_{M_{Na_2SO_4}}=\dfrac{0,095}{0,04+0,095}\approx0,7M\\ c)Cu\left(OH\right)_2\xrightarrow[t^0]{}CuO+H_2O\)

0,095                 0,095

\(m_{rắn}=m_{CuO}=0,095.80=7,6g\)

a)b)c)d) mBaCl2=150.16,64%=24,96g

=>nBaCl2=0,12 mol

mH2SO4=100.14,7%=14,7g=>nH2SO4=0,15mol

     BaCl2       + H2SO4 =>BaSO4    +2HCl

Bđ: 0,12 mol;    0,15 mol

Pứ: 0,12 mol=>0,12 mol=>0,12 mol=>0,24 mol

Dư:                   0,03 mol

Dd ban đầu chứa BaCl2 0,12 mol và H2SO4 0,15 mol

Dd A sau phản ứng chứa HCl 0,24 mol và H2SO4 dư 0,03 mol

mHCl=0,24.36,5=8,76g

mH2SO4=0,03.98=2,94g

Kết tủa B là BaSO4 0,12 mol=>mBaSO4=0,12.233=27,96g

mddA=mddBaCl2+mddH2SO4-mBaSO4

=150+100-27,96=222,04g

C%dd HCl=8,76/222,04.100%=3,945%

C% dd H2SO4=2,94/222,04.100%=1,324%

e) HCl     +NaOH =>NaCl +H2O

0,24 mol=>0,24 mol

H2SO4 +2NaOH =>Na2SO4 + 2H2O

0,03 mol=>0,06 mol

TÔNG nNaOH=0,3 mol

=>V dd NaOH=0,3/2=0,15 lit

\(a,PTHH:FeCl_3+3NaOH\rightarrow Fe\left(OH\right)_3\downarrow+3NaCl\\ \Rightarrow n_{Fe\left(OH\right)_2}=n_{FeCl_3}=\dfrac{10,7}{107}=0,1\left(mol\right)\\ \Rightarrow m_{CT_{FeCl_3}}=0,1\cdot162,5=16,25\left(g\right)\\ \Rightarrow m_{dd_{FeCl_3}}=\dfrac{16,25\cdot100\%}{5\%}=325\left(g\right)\\ b,n_{NaOH}=n_{NaCl}=3n_{Fe\left(OH\right)_3}=0,3\left(mol\right)\\ \Rightarrow m_{NaOH}=0,3\cdot40=12\left(g\right)\\ m_{NaCl}=0,3\cdot58,5=17,55\left(g\right)\\ \Rightarrow m_{dd_{NaCl}}=325+150-10,7=464,3\left(g\right)\\ \Rightarrow C\%_{dd_{NaCl}}=\dfrac{17,55}{464,3}\cdot100\%\approx3,78\%\)