\(a,PTHH:FeCl_3+3NaOH\rightarrow Fe\left(OH\right)_3\downarrow+3NaCl\\ \Rightarrow n_{Fe\left(OH\right)_2}=n_{FeCl_3}=\dfrac{10,7}{107}=0,1\left(mol\right)\\ \Rightarrow m_{CT_{FeCl_3}}=0,1\cdot162,5=16,25\left(g\right)\\ \Rightarrow m_{dd_{FeCl_3}}=\dfrac{16,25\cdot100\%}{5\%}=325\left(g\right)\\ b,n_{NaOH}=n_{NaCl}=3n_{Fe\left(OH\right)_3}=0,3\left(mol\right)\\ \Rightarrow m_{NaOH}=0,3\cdot40=12\left(g\right)\\ m_{NaCl}=0,3\cdot58,5=17,55\left(g\right)\\ \Rightarrow m_{dd_{NaCl}}=325+150-10,7=464,3\left(g\right)\\ \Rightarrow C\%_{dd_{NaCl}}=\dfrac{17,55}{464,3}\cdot100\%\approx3,78\%\)