a, Ta có: \(n_{Al}=\dfrac{5,4}{27}=0,2\left(mol\right)\)
\(n_{HCl}=\dfrac{109,5.10\%}{36,5}=0,3\left(mol\right)\)
PT: \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)
Xét tỉ lệ: \(\dfrac{0,2}{2}>\dfrac{0,3}{6}\), ta được Al dư.
Theo PT: \(n_{H_2}=\dfrac{1}{2}n_{HCl}=0,15\left(mol\right)\)
\(\Rightarrow V_{H_2}=0,15.24,79=3,7185\left(l\right)\)
b, \(n_{Al\left(pư\right)}=n_{AlCl_3}=\dfrac{1}{3}n_{HCl}=0,1\left(mol\right)\)
Ta có: m dd sau pư = 0,1.27 + 109,5 - 0,15.2 = 111,9 (g)
\(\Rightarrow C\%_{AlCl_3}=\dfrac{0,1.133,5}{111,9}.100\%\approx11,9\%\)