Cù Văn Thái again lại nè, a xem đúng k :)
TH1: NaOH hết, AlCl3 dư
\(PTHH:3NaOH+AlCl_3\rightarrow3NaCl+Al\left(OH\right)_3\)
(mol)______0,3________________________0,1__
\(n_{Al\left(OH\right)_3}=\frac{7,8}{78}=0,1\left(mol\right)\)
\(V_{NaOH}=\frac{0,3}{0,4}=0,75\left(l\right)\)
TH2: NaOH dư, AlCl3 hết
\(n_{AlCl_3}=0,8.0,5=0,4\left(mol\right)\)
\(PTHH:3NaOH+AlCl_3\rightarrow Al\left(OH\right)_3+3NaCl\)
(mol)______0,12______0,4________0,4_________
Gọi x là số mol kết tủa bị hòa tan
\(PTHH:Al\left(OH\right)_3+NaOH\rightarrow NaAlO_2+2H_2O\)
(mol)________x_______x_______________________
Theo đề bài ta có:
\(0,4-x=\frac{7,8}{78}\)
\(\Leftrightarrow x=0,4-0,1=0,3\left(mol\right)\)
\(n_{NaOH}=0,12+0,3=0,15\left(mol\right)\)
\(V_{NaOH}=\frac{0,15}{0,4}=0,375\left(l\right)\)
\(n_{\downarrow}=\frac{7,8}{78}=0,1\left(mol\right)\)
\(PTHH:3NaOH+AlCl_3\rightarrow3NaCl+Al\left(OH\right)_3\downarrow\)
(mol)_______3_________________________1______
(mol)_______0,3_______________________0,1_____
\(V_{ddNaOH}=\frac{0,3}{0,4}=0,75\left(l\right)\)