\(Đặt:V_{ddHCl}=V_{ddKOH}=a\left(l\right)\\ \Rightarrow n_{HCl}=0,01a\left(mol\right)\\ n_{KOH}=0,03a\left(mol\right)\\ HCl+KOH\rightarrow KCl+H_2O\\ Vì:\dfrac{0,01a}{1}< \dfrac{0,03a}{1}\Rightarrow KOHdư\\ \Rightarrow n_{KOH\left(dư\right)}=0,03a-0,01a=0,02a\left(mol\right)\\ \left[OH^-\left(dư\right)\right]=\left[KOH\left(dư\right)\right]=\dfrac{0,02a}{a+a}=0,01\left(M\right)\\ \Rightarrow pH=14+log\left[0,01\right]=12\)