\(a,n_{CO_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\\ n_{\left(CH_3COO\right)_2Ba}=\dfrac{127,5}{255}=0,5\left(mol\right)\)
PTHH: \(BaCO_3+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Ba+CO_2\uparrow+H_2O\)
0,2<-------0,4<-----------------0,2<----------------0,2
\(\rightarrow n_{\left(CH_3COO\right)_2Ba\left(BaO\right)}=0,5-0,2=0,3\left(mol\right)\)
PTHH: \(BaO+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Ba+H_2O\)
0,3<----0,15<---------------0,3
\(\rightarrow\left\{{}\begin{matrix}m_{BaCO_3}=0,2.197=39,4\left(g\right)\\m_{BaO}=0,3.153=45,9\left(g\right)\end{matrix}\right.\)
\(b,V_{dd}=\dfrac{0,15+0,4}{1,5}=\dfrac{11}{30}\left(l\right)\\ \rightarrow C_{M\left(\left(CH_3COO\right)_2Ba\right)}=\dfrac{0,5}{\dfrac{11}{30}}=\dfrac{15}{11}M\)