Gọi \(\left\{{}\begin{matrix}n_{NO_2}=x\left(mol\right)\\n_{NO}=y\left(mol\right)\end{matrix}\right.\)
\(n_{hhkhí}=\dfrac{4,48}{22,4}=0,2mol\) \(\Rightarrow x+y=0,2\left(1\right)\)
\(d_{\dfrac{khí}{H_2}}=18,2\Rightarrow M_{khí}=18,2\cdot2=36,4\)
Sơ đồ chéo: \(NO_2:46\) 6,4
36,4
\(NO:30\) 9,6
\(\Rightarrow\dfrac{x}{y}=\dfrac{6,4}{9,6}=\dfrac{2}{3}\left(2\right)\)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{NO_2}=x=0,08mol\\n_{NO}=y=0,12mol\end{matrix}\right.\)
\(\underrightarrow{BTe:}\) \(3n_{Fe}=n_{NO_2}+3n_{NO}=0,08+3\cdot0,12=0,44mol\)
\(\Rightarrow n_{Fe}=\dfrac{11}{75}mol\Rightarrow m_{Fe}=\dfrac{616}{75}\left(g\right)\)
\(m_{muối}=m_{Fe}+62n\left(e\right)=\dfrac{616}{75}+62\cdot\left(0,08+0,12\cdot3\right)=35,5\left(g\right)\)
