Câu 4:
PTHH: \(NaBr+AgNO_3\rightarrow NaNO_3+AgBr\downarrow\)
a) Ta có: \(n_{AgBr}=\dfrac{37,6}{188}=0,2\left(mol\right)=n_{NaBr}\)
\(\Rightarrow\%m_{NaBr}=\dfrac{0,2\cdot103}{42,6}\cdot100\%\approx48,37\%\) \(\Rightarrow\%m_{NaF}=51,63\%\)
b) Ta có: \(\Sigma n_{AgNO_3}=\dfrac{850\cdot1,09\cdot10\%}{170}=0,545\left(mol\right)\)
\(\Rightarrow n_{AgNO_3\left(dư\right)}=0,345\left(mol\right)\) \(\Rightarrow m_{AgNO_3\left(dư\right)}=0,345\cdot170=58,65\left(g\right)\)
Theo PTHH: \(m_{NaNO_3}=0,2\cdot85=17\left(g\right)\)
Mặt khác: \(\left\{{}\begin{matrix}m_{NaF}=42,6-0,2\cdot103=22\left(g\right)\\m_{dd}=m_{hh}+m_{ddAgNO_3}-m_{AgBr}=931,5\left(g\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{AgNO_3\left(dư\right)}=\dfrac{58,65}{931,5}\cdot100\%\approx6,3\%\\C\%_{NaF}=\dfrac{22}{931,5}\cdot100\%\approx2,36\%\\C\%_{NaNO_3}=\dfrac{17}{931,5}\cdot100\%\approx1,83\%\end{matrix}\right.\)