\(\left\{{}\begin{matrix}n_{HCl}=0,1\left(mol\right)\\n_{AlCl3}=0,2\left(mol\right)\\n_{Al\left(OH\right)3}=0,1\left(mol\right)\end{matrix}\right.\)
Tạo kết tủa => HCl bị trung hoà hết
\(NaOH+HCl\rightarrow NaCl+H_2O\)
\(\Rightarrow n_{NaOH\left(trung.hoa\right)}=0,1\left(mol\right)\)
- TH1: dư AlCl3
\(AlCl_3+3NaOH\rightarrow Al\left(OH\right)_3+3NaCl\)
\(\Rightarrow n_{NaOH}=0,3\left(mol\right)\)
\(\Rightarrow\Sigma n_{NaOH}=0,4\left(mol\right)\)
\(\Rightarrow V=0,4\left(l\right)=400\left(ml\right)\)
- TH2: dư NaOH
\(AlCl_3+3NaOH\rightarrow Al\left(OH\right)_3+3NaCl\)
=> 0,2 mol AlCl3 tạo 0,2 mol Al(OH)3. Có 0,6 mol NaOH phản ứng
=> 0,2-0,1= 0,1 mol Al(OH)3 tan
\(Al\left(OH\right)_3+NaOH\rightarrow NaAlO_2+2H_2O\)
\(\Rightarrow n_{NaOH}=0,1\left(mol\right)\)
\(\Rightarrow\Sigma n_{NaOH}=0,8\left(mol\right)\)
\(\Rightarrow V=0,8\left(l\right)=800\left(ml\right)\)