nZnO=8.1/81=0.1
nH2SO4=(mdd.C%)/(100.M)=(200.10)/(100.98)=0.2
a)ZnO + H2SO4 --> ZnSO4 + H2O
0.1 ---->0.1---->0.1--->0.1
LTL: 0.1/1 < 0.2/1 ==> H2SO4 dư
áp dụng định luật bảo toàn khối lượng ta có
mddZnSO4=mZnO+mddH2SO4=8.1+200=208.1g
==>C%ZnSO4=(0,1.160).100/208.1=7.69%
nH2SO4 dư = 0.2-0.1=0.1
C%H2SO4dư=(0,1.98).100/208.1=4.71%
nZnO= 8,1/81=0.1(mol)
nH2SO4= 200.10/100.98=0.2(mol)
ZnO + H2SO4 -> ZnSO4 +H2O
đề 0,1 0,2
pứ 0,1 0,1 0,1
dư 0 0,1
mddspu = 8,1+200=208,1(g)
C%ZnSO4=0,1.161.100/208,1=7,74%
C%H2SO4 dư= 0.1.98.100/208,1=4,71%
ZnO + H2SO4 → ZnSO4 + H2O
\(n_{ZnO}=\dfrac{8,1}{81}=0,1\left(mol\right)\)
\(m_{H_2SO_4}=200\times10\%=20\left(g\right)\)
\(\Rightarrow n_{H_2SO_4}=\dfrac{20}{98}=\dfrac{10}{49}\left(mol\right)\)
Theo PT: \(n_{ZnO}=n_{H_2SO_4}\)
Theo bài: \(n_{ZnO}=\dfrac{49}{100}n_{H_2SO_4}\)
Vì \(\dfrac{49}{100}< 1\) ⇒ ZnO hết, H2SO4 dư
Dung dịch sau phản ứng gồm: H2SO4 dư, ZnSO4
Theo PT: \(n_{H_2SO_4}pư=n_{ZnO}=0,1\left(mol\right)\)
\(\Rightarrow n_{H_2SO_4}dư=\dfrac{10}{49}-0,1=\dfrac{51}{490}\left(mol\right)\)
\(\Rightarrow m_{H_2SO_4}dư=\dfrac{51}{490}\times98=10,2\left(g\right)\)
Theo PT: \(n_{ZnSO_4}=n_{ZnO}=0,1\left(mol\right)\)
\(\Rightarrow m_{ZnSO_4}=0,1\times161=16,1\left(g\right)\)
\(\Sigma m_{dd}=8,1+200=208,1\left(g\right)\)
\(\Rightarrow C\%_{H_2SO_4}dư=\dfrac{10,2}{208,1}\times100\%=4,9\%\)
\(C\%_{ZnSO_4}=\dfrac{16,1}{208,1}\times100\%=7,7\%\)