\(\text{a) }n_{CaCl_2}=\dfrac{m}{M}=\dfrac{2,22}{111}=0,02\left(mol\right)\\ \Rightarrow C_{M\left(CaCl_2\right)}=\dfrac{0,02}{0,1}=0,2\left(M\right)\)
\(\text{b) }n_{H_2SO_4}=C_M\cdot V=0,04\cdot8=0,32\left(mol\right)\\ \Rightarrow C_{M\left(H_2SO_4\right)}=\dfrac{n}{V}=\dfrac{0,32}{0,16}=2\left(M\right)\)