Bài 1:
2KMnO4 \(\underrightarrow{to}\) K2MnO4 + MnO2 + O2
\(n_{KMnO_4}=\dfrac{31,6}{158}=0,2\left(mol\right)\)
Theo PT: \(n_{O_2}lt=\dfrac{1}{2}n_{KMnO_4}=\dfrac{1}{2}\times0,2=0,1\left(mol\right)\)
Do \(H=90\%\) \(\Rightarrow n_{O_2}tt=0,1\times90\%=0,09\left(mol\right)\)
\(\Rightarrow V_{O_2}tt=0,09\times22,4=2,016\left(l\right)\)
Bài 2:
2KClO3 \(\underrightarrow{to}\) 2KCl + 3O2
\(n_{O_2}tt=\dfrac{33,6}{22,4}=1,5\left(mol\right)\)
\(\Rightarrow n_{O_2}lt=\dfrac{1,5}{\left(100\%-10\%\right)}=1,667\left(mol\right)\)
Theo PT: \(n_{KClO_3}=\dfrac{2}{3}n_{O_2}lt=\dfrac{2}{3}\times1,667=1,1113\left(mol\right)\)
\(\Rightarrow m_{KClO_3}=1,1113\times122,5=136,13425\left(g\right)\)
1)
\(n_{KMnO_4}=\dfrac{31,6}{158}=0,2\left(mol\right)\)
PTHH: \(2KMnO_4\rightarrow MnO_2+O_2\uparrow+K_2MnO_4\)
Theo PT ta có: \(n_{O_2\left(lt\right)}=\dfrac{0,2.1}{2}=0,1\left(mol\right)\)
Theo đề bài hiệu suất phản ứng = 90%:
\(\Rightarrow n_{O_2\left(tt\right)}=0,1.90\%=0,09\left(mol\right)\)
Thể tích khí O2 thu được ở đktc:
\(\Rightarrow V_{O_2\left(tt\right)\left(đktc\right)}=0,09.22,4=2,016\left(l\right)\)