\(Câu20:\)
\(TN1:\)
\(Đặt:n_{Cu}=x\left(mol\right),n_{Zn}=y\left(mol\right)\)
\(m_{hh}=135x+136y=81.36\left(g\right)\left(.\right)\)
\(TN2:\)
\(Đặt:n_{Cu}=kx\left(mol\right),n_{Zn}=ky\left(mol\right),n_{Al}=kz\left(mol\right)\)
\(n_X=kx+ky=0.5\left(mol\right)\left(1\right)\)
\(\dfrac{n_{Zn}}{n_{Al}}=\dfrac{3}{2}\Rightarrow\dfrac{ky}{kz}=\dfrac{3}{2}\Rightarrow2ky-3kz=0\left(2\right)\)
\(n_{H_2}=ky+1.5kz=\dfrac{13.44}{22.4}=0.6\left(mol\right)\left(3\right)\)
\(\left(1\right),\left(2\right),\left(3\right):\)\(kx=0.2,ky=0.3,kz=0.2\)
\(Từ\left(.\right):\)
\(\Rightarrow135\left(x+y\right)+y=81.36\)
\(\Leftrightarrow135\cdot\dfrac{0.5}{k}+\dfrac{0.3}{k}=81.36\)
\(\Leftrightarrow k=\dfrac{135\cdot0.5+0.3}{81.36}=\dfrac{5}{6}\)
\(KĐ:\)
\(x=0.24,y=0.36\)
\(m_{Cu}=0.24\cdot64=15.36\left(g\right)\)
=> B
Giải hơi dài nhưng em xem thử nhé !!
\(n_{Cu} = a(mol;n_{Zn} = b(mol)\\ Cu + Cl_2 \xrightarrow{t^o} CuCl_2\\ Zn + Cl_2 \xrightarrow{t^o} ZnCl_2\\ \Rightarrow 135a + 136b = 81,36(1)\)
Trong 0,5 mol X có chứa ak mol Cu và bk mol Zn (k>0)
Suy ra:
\(n_{Al} = \dfrac{2}{3}n_{Zn} = \dfrac{2}{3}bk(mol)\\ Zn + 2HCl \to ZnCl_2 + H_2\\ 2Al + 6HCl \to 2AlCl_3 + 3H_2\\ n_{H_2} = bk + \dfrac{2}{3}bk. \dfrac{3}{2} = \dfrac{13,44}{22,4} = 0,6(mol)\\ \Rightarrow bk = 0,3\\ \Rightarrow ak = 0,5 - 0,3 = 0,2\\ \Rightarrow \dfrac{a}{b} = \dfrac{ak}{bk} = \dfrac{0,2}{0,3}= \dfrac{2}{3}(2)\)
Từ (1)(2) suy ra: a = 0,24 ; b =0,36
Vậy : \(m_{Cu} = 0,24.64 = 15,36(gam)\)
Đáp án D
Câu20:Câu20:
TN1:TN1:
Đặt:nCu=x(mol),nZn=y(mol)Đặt:nCu=x(mol),nZn=y(mol)
mhh=135x+136y=81.36(g)(.)mhh=135x+136y=81.36(g)(.)
TN2:TN2:
Đặt:nCu=kx(mol),nZn=ky(mol),nAl=kz(mol)Đặt:nCu=kx(mol),nZn=ky(mol),nAl=kz(mol)
nX=kx+ky=0.5(mol)(1)nX=kx+ky=0.5(mol)(1)
nH2=ky+1.5kz=13.4422.4=0.6(mol)(3)nH2=ky+1.5kz=13.4422.4=0.6(mol)(3)
(1),(2),(3):(1),(2),(3):kx=0.2,ky=0.3,kz=0.2kx=0.2,ky=0.3,kz=0.2
Từ(.):Từ(.):
⇒135(x+y)+y=81.36⇒135(x+y)+y=81.36
⇔k=135⋅0.5+0.381.36=56⇔k=135⋅0.5+0.381.36=56
KĐ:KĐ:
x=0.24,y=0.36x=0.24,y=0.36
mCu=0.24⋅64=15.36(g)mCu=0.24⋅64=15.36(g)
=> B