Câu 6:
a, PT: \(Mg+2HCl\rightarrow MgCl_2+H_2\)
\(Zn+2HCl\rightarrow ZnCl_2+H_2\)
Gọi: \(\left\{{}\begin{matrix}n_{Mg}=x\left(mol\right)\\n_{Zn}=y\left(mol\right)\end{matrix}\right.\) ⇒ 24x + 65y = 19,85 (1)
Theo PT: \(\left\{{}\begin{matrix}n_{MgCl_2}=n_{Mg}=x\left(mol\right)\\n_{ZnCl_2}=n_{Zn}=y\left(mol\right)\end{matrix}\right.\)
\(n_{HCl\left(pư\right)}=2n_{Mg}+2n_{Zn}=2x+2y\left(mol\right)\)
⇒ nHCl (dư) = (2x + 2y).20% (mol)
⇒ 95x + 136y + (2x + 2y).20%.36,5 = 54,09 (2)
Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}x=0,15\left(mol\right)\\y=0,25\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}\%m_{Mg}=\dfrac{0,15.24}{19,85}.100\%\approx18,14\%\\\%m_{Zn}\approx81,86\%\end{matrix}\right.\)
b, Ta có: nHCl (pư) = 0,15.2 + 0,25.2 = 0,8 (mol) ⇒ nH2 = 1/2nHCl = 0,4 (mol)
nHCl (dư) = 0,8.20% = 0,16 (mol)
\(\Rightarrow m_{ddHCl}=\dfrac{\left(0,8+0,16\right).36,5}{29,2\%}=120\left(g\right)\)
⇒ m dd sau pư = 19,85 + 120 - 0,4.2 = 139,05 (g)
\(\Rightarrow\left\{{}\begin{matrix}C\%_{HCl}=\dfrac{0,16.36,5}{139,05}.100\%\approx4,20\%\\C\%_{MgCl_2}=\dfrac{0,15.95}{139,05}.100\%\approx10,25\%\\C\%_{ZnCl_2}=\dfrac{0,25.136}{139,05}.100\%\approx24,45\%\end{matrix}\right.\)