80 gam dung dịch A chứa 3,52 gam NaOH

=> 200 gam dung dịch A chứa 3,52.200/80 = 8,8 gam

n NaOH = 8,8/40 = 0,22(mol)

Gọi n Na = a(mol) ; n Na2O = b(mol)

=> 23a + 62b = 6,02(1)

$2Na + 2H_2O \to 2NaOH + H_2$
$Na_2O + H_2O \to 2NaOH$
n NaOH = a + 2b = 0,22(2)

Từ (1)(2) suy ra  a= 0,1 ; b = 0,06

n H2 = 0,5a = 0,05(mol)

=> m H2O = 200 + 0,05.2 - 6,02 =194,08(gam)

%m Na = 0,1.23/6,02   .100% = 38,2%

%m Na2O = 100% -38,2% = 61,8%

Coi X gồm Na, Ba và O.

Ta có: \(n_{Ba\left(OH\right)_2}=\dfrac{20,52}{171}=0,12\left(mol\right)\)

BTNT Ba, có: n_Ba = n_Ba(OH)2 = 0,12 (mol)

Gọi: \(\left\{{}\begin{matrix}n_{Na}=x\left(mol\right)\\n_O=y\left(mol\right)\end{matrix}\right.\) ⇒ 23x + 16y = 21,9 - 0,12.137 (1)

Ta có: \(n_{H_2}=\dfrac{1,12}{22,4}=0,05\left(mol\right)\)

BT e, có: n_Na + 2n_Ba = 2n_O + 2n_H2 ⇒ x + 0,12.2 = 2y + 0,05.2 (2)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}x=0,14\left(mol\right)\\y=0,14\left(mol\right)\end{matrix}\right.\)

BTNT Na, có: n_NaOH = n_Na = 0,14 (mol) 

⇒ m = m_NaOH = 0,14.40 = 5,6 (g)

a)

n O = 6,13.23,491%/16 = 0,09(mol)

=> n Al2O3 = 1/3 n O = 0,03(mol)

n H2 = 1,456/22,4 = 0,065(mol)

$H_2O \to OH^- + \dfrac{1}{2}H_2$

Suy ra:  n OH = 2n H2 = 0,065.2 = 0,13(mol)

Al₂O₃ + 2OH^- → 2AlO₂^- + H₂O

0,03......0,06..........0,06.....................(mol)

DUng dịch G có : 

AlO2- : 0,06

OH- : 0,13 - 0,06 = 0,07(mol)

Áp dụng CT : 

n H+ = 4n AlO2- + n OH- - 3n Al(OH)3

<=> 0,16 = 0,06.4 + 0,07 - 3n Al(OH)3

<=> n Al(OH)3 = 0,05(mol)

<=> m = 0,05.78 = 3,9(gam)

Trong F : 

m Na + m K + m Ba = m D - m Al2O3 = 6,13 - 0,03.102 = 3,07(gam)

n Cl = n HCl = 0,16(mol)

n Al3+ = 0,06 - 0,05 = 0,01(mol)

=> m chất tan = 3,07 + 0,16.35,5 + 0,01.27 = 9,02(gam)

PTHH: \(Na+H_2O\rightarrow NaOH+\dfrac{1}{2}H_2\uparrow\)

            \(Na_2O+H_2O\rightarrow2NaOH\)

Ta có: \(\left\{{}\begin{matrix}n_{NaOH}=n_{Na}+2n_{Na_2O}=\dfrac{4,6}{23}+2\cdot\dfrac{6,2}{62}=0,3\left(mol\right)\\n_{H_2}=\dfrac{1}{2}n_{Na}=0,05\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{NaOH}=0,3\cdot40=12\left(g\right)\\m_{H_2}=0,05\cdot2=0,1\left(g\right)\end{matrix}\right.\)

Mặt khác: \(m_{dd\left(sau.p/ứ\right)}=m_{Na}+m_{Na_2O}+m_{H_2O}-m_{H_2}=110,7\left(g\right)\)

\(\Rightarrow C\%_{NaOH}=\dfrac{12}{110,7}\cdot100\%\approx10,84\%\)

Theo gt ta có: $n_{Na}=0,2(mol);n_{Na_2O}=0,1(mol)$

$2Na+2H_2O\rightarrow 2NaOH+H_2$

$Na_2O+H_2O\rightarrow 2NaOH$

Ta có: $n_{NaOH}=0,4(mol);n_{H_2}=0,1(mol)$

Bảo toàn khối lượng ta có: $m_{dd}=110,6(g)$

$\Rightarrow \%C_{NaOH}=14,46\%$

\(n_{Na}=\dfrac{m}{M}=0,2mol\)

\(n_{Na2O}=\dfrac{m}{M}=0,1\left(mol\right)\)

\(BTNT\left(Na\right):n_{NaOH}=0,2+2.0,1=0,4\left(mol\right)\)

\(\Rightarrow m_{NaOH}=n.M=16g\)

\(PTHH:Na+H_2O\rightarrow NaOH+\dfrac{1}{2}H_2\)

...............0,2...................................0,1.

\(\Rightarrow m_{dd}=m_{KL}+m_{H2O}-m_{H2}=110,6g\)

\(\Rightarrow C\%_{NaOH}=\dfrac{m}{m_{dd}}.100\%=14,46\%\)

a) 

2NaOH + 2H₂O --> 2NaOH + H₂

2K + 2H₂O --> 2KOH + H₂

b)

\(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)

Gọi số mol Na, K là a, b 

=> 23a + 39b = 6,2

PTHH: 2NaOH + 2H₂O --> 2NaOH + H₂

_______a------------------------------->0,5a

2K + 2H₂O --> 2KOH + H₂

b------------------------->0,5b

=> 0,5a + 0,5b = 0,1

=> a = 0,1; b = 0,1

=> \(\left\{{}\begin{matrix}\%Na=\dfrac{0,1.23}{6,2}.100\%=37,097\%\\\%K=\dfrac{0,1.39}{6,2}.100\%=62,903\%\end{matrix}\right.\)

Chọn đáp án C