PTHH: \(Na+H_2O\rightarrow NaOH+\dfrac{1}{2}H_2\uparrow\)
\(Na_2O+H_2O\rightarrow2NaOH\)
Ta có: \(\left\{{}\begin{matrix}n_{NaOH}=n_{Na}+2n_{Na_2O}=\dfrac{4,6}{23}+2\cdot\dfrac{6,2}{62}=0,3\left(mol\right)\\n_{H_2}=\dfrac{1}{2}n_{Na}=0,05\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{NaOH}=0,3\cdot40=12\left(g\right)\\m_{H_2}=0,05\cdot2=0,1\left(g\right)\end{matrix}\right.\)
Mặt khác: \(m_{dd\left(sau.p/ứ\right)}=m_{Na}+m_{Na_2O}+m_{H_2O}-m_{H_2}=110,7\left(g\right)\)
\(\Rightarrow C\%_{NaOH}=\dfrac{12}{110,7}\cdot100\%\approx10,84\%\)
Theo gt ta có: $n_{Na}=0,2(mol);n_{Na_2O}=0,1(mol)$
$2Na+2H_2O\rightarrow 2NaOH+H_2$
$Na_2O+H_2O\rightarrow 2NaOH$
Ta có: $n_{NaOH}=0,4(mol);n_{H_2}=0,1(mol)$
Bảo toàn khối lượng ta có: $m_{dd}=110,6(g)$
$\Rightarrow \%C_{NaOH}=14,46\%$
\(n_{Na}=\dfrac{m}{M}=0,2mol\)
\(n_{Na2O}=\dfrac{m}{M}=0,1\left(mol\right)\)
\(BTNT\left(Na\right):n_{NaOH}=0,2+2.0,1=0,4\left(mol\right)\)
\(\Rightarrow m_{NaOH}=n.M=16g\)
\(PTHH:Na+H_2O\rightarrow NaOH+\dfrac{1}{2}H_2\)
...............0,2...................................0,1.
\(\Rightarrow m_{dd}=m_{KL}+m_{H2O}-m_{H2}=110,6g\)
\(\Rightarrow C\%_{NaOH}=\dfrac{m}{m_{dd}}.100\%=14,46\%\)
