\(n_C=\dfrac{1.2}{12}=0.1\left(mol\right)\\ n_S=\dfrac{4}{32}=0.125\left(mol\right)\)
\(2KMnO_4\underrightarrow{t^0}K_2MnO_4+MnO_2+O_2\)
\(C+O_2\underrightarrow{t^0}CO_2\)
\(S+O_2\underrightarrow{t^0}SO_2\)
\(\sum n_{O_2}=n_C+n_S=0.1+0.125=0.225\left(mol\right)\)
\(\Rightarrow n_{KMnO_4}=2n_{O_2}=0.225\cdot2=0.45\left(mol\right)\)
\(m_{KMnO_4}=0.45\cdot158=71.1\left(g\right)\)
2KMnO4 -to>K2MnO4+O2+MnO2
0,45------------------------0,225
C+O2-to>CO2
0,1--0,1
S+O2-to>SO2
0,125-0,125
n C=1,2\12=0,1 mol
n S=4\32=0,125 mol
=>m KMnO4=0,45.158=77,1g