\(pthh:2Zn+O_2\overset{t^0}{\rightarrow}2ZnO\left(1\right)\)
\(n_{ZnO}=\dfrac{m}{M}=\dfrac{40,5}{81}0,5\left(mol\right)\)
Theo \(pthh\left(1\right):n_{O_2}=\dfrac{1}{2}n_{ZnO}=\dfrac{1}{2}\cdot0,5=0,25\left(mol\right)\)
\(\Rightarrow m_{O_2}=n\cdot M=0,25\cdot32=8\left(g\right)\)
\(2KClO_3\overset{t^0}{\rightarrow}2KCl+3O_2\left(2\right)\)
Theo \(pthh\left(2\right):n_{KClO_3}=\dfrac{2}{3}n_{O_2}=\dfrac{2}{3}\cdot0,25=\dfrac{1}{3}\left(mol\right)\)
\(\Rightarrow m_{KClO_3}=n\cdot M=\dfrac{1}{3}\cdot122,5=40,83\left(g\right)\)