a) PTHH: NaOH + Al + H2O -> NaAlO2 + 3/2 H2
b) nH2= 0,6(mol)
-> nAl=0,4(mol) => mAl=0,4.27=10,8(g)
c) nAl=0,18((mol); nNaOH=0,2(mol)
PTHH: 0,18/1 < 0,2/1
=> Al hết, NaOH dư, tính theo nAl.
-> nH2= 3/2. 0,18=0,27(mol)
=>V(H2,đktc)=0,27.22,4= 6,048(l)
\(n_{H_2}=\dfrac{13.44}{22.4}=0.6\left(mol\right)\)
\(2NaOH+2Al+2H_2O\rightarrow2NaAlO_2+3H_2\)
\(...........0.4.........................0.6\)
\(m_{Al}=0.4\cdot27=10.8\left(g\right)\)
\(n_{Al}=\dfrac{4.86}{27}=0.18\left(mol\right)\)
\(n_{NaOH}=\dfrac{8}{40}=0.2\left(mol\right)\)
\(2NaOH+2Al+2H_2O\rightarrow2NaAlO_2+3H_2\)
\(2.................2\)
\(0.2...............0.18\)
\(LTL:\dfrac{0.2}{2}>\dfrac{0.18}{2}\)
\(\Rightarrow NaOHdư\)
\(n_{H_2}=0.18\cdot\dfrac{3}{2}=0.27\left(mol\right)\)
\(V_{H_2}=0.27\cdot22.4=6.048\left(l\right)\)
a, PTHH: 2NaOH + 2Al + 2H2O → 2NaAlO2 + 3H2↑
b, nH2=0,6 mol -mAl=10,8 g
c, nAl=0,16(592) mol
nNaOH=0,2 mol
-NaOH hết, Al dư
-VH2=6,72 l