gọi x là khối lượng MgO (g), khối lượng ZnO là 2,025x (g)
ta có:
\(m_{mgO}+m_{ZnO}=12,1\Leftrightarrow x+2,025x=12,1\\ \Leftrightarrow3,025x=12,1\\ \Leftrightarrow x=\dfrac{12,1}{3,025}=4\left(g\right)\\ m_{MgO}=4\left(g\right)\Rightarrow m_{ZnO}=2,025\cdot4=8,1\left(g\right)\)
ta có PTHH(1): \(2Mg+O_2-t^0\rightarrow2MgO_{ }\)
theo gt:
\(n_{MgO}=\dfrac{4}{40}=0,1\left(mol\right)\\ theoPTHH:n_{O2}=2n_{MgO}=\dfrac{1}{2}.0,1=0,05\left(mol\right)\\ n_{Mg}=n_{MgO}=0,1\left(mol\right)\Rightarrow m_{Mg}=o,1\cdot24=2,4\left(g\right)\)
PTHH(2):
\(2Zn+O_2-t^0\rightarrow2ZnO\\ theogt:n_{ZnO}=\dfrac{8,1}{81}=0,1\left(mol\right)\\ theoPTHH:n_{O2}=\dfrac{1}{2}n_{ZnO}=\dfrac{1}{2}0,1=0,05\left(mol\right)\\ n_{Zn}=n_{ZnO}=0,1\left(mol\right)\Rightarrow m_{Zn}=0,1\cdot65=6,5\left(g\right)\)
từ PTHH(1) và (2) \(\Rightarrow n_{O2}=0,05+0,05=0,1\left(mol\right)\\ \Rightarrow V_{O2}=0,1\cdot22,4=2,24\left(l\right)\Rightarrow V_{kk}=2,24\cdot5=11,2\left(l\right)\)
Gọi nMg= x ; nZn= y (x , y >0)
PTHH :
2Mg + O2\(\dfrac{t^o}{ }\)> 2MgO (1)
x ---->\(\dfrac{x}{2}\) ----->x
2Zn + O2 \(\dfrac{t^o}{ }\)> 2ZnO (2)
y---->\(\dfrac{y}{2}\)------>y
Theo đề bài ta có :
40x + 81y = 12,1
và 81y = 2,025 . 40x
=> x = 0,1 ; y = 0,1
Theo pt (1) nMg=nMgO= 0,1 mol
=> mMg = 2,4 g
Theo pt (2) nZn=nZnO=0,1 mol
=> mZn = 6,5 g
mhh = 2,4+ 6,5 = 8,9 g
%Mg =\(\dfrac{2,4}{8,9}\) =26,97 %
%Zn = 100% - 26,97% = 73,03 %
VO2=nO2 . 22,4 = ......
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