\(n_{CaCO_3}=\dfrac{7}{100}=0,07\left(mol\right)\)
\(n_{HCl}=\dfrac{5,475}{36,5}=0,15\left(mol\right)\)
PTHH: CaCO3 + 2HCl --> CaCl2 + CO2 + H2O
Xét \(\dfrac{n_{CaCO_3}}{1}=0,07< \dfrac{n_{HCl}}{2}=0,075\)
=> HCl dư
Do đó, ta có:
PTHH: CaCO3 + 2HCl --> CaCl2 + CO2 + H2O
_______0,075<---0,15__________________________(mol)
=> \(m_{CaCO_3\left(cầnthêm\right)}=\left(0,075-0,07\right).100=0,5\left(g\right)\)