Ta vó nH2 = \(\dfrac{13,44}{22,4}\) = 0,6 ( mol )
2Al + 6HCl \(\rightarrow\) 2AlCl3 + 3H2
0,4.......0,6...........0,4........0,6
=> mAl = 27 . 0,4 = 10,8 ( gam )
=> %mAl = \(\dfrac{10,8}{27}\) . 100 = 40 %
=> %mZn = 100 - 40 = 60 %
=> mZnO = 27 - 10,8 = 16,2 ( gam )
=> nZnO = \(\dfrac{16,2}{81}\) = 0,2 ( mol )
ZnO + 2HCl \(\rightarrow\) ZnCl2 + H2O
0,2........0,4.........0,2
=> mHCl = ( 0,4 + 0,6 ) . 36,5 = 36,5 ( gam )
=> mHCl cần dùng = 36,5 : 29,2 . 100 = 125 ( gam )
=> mAlCl3 = 0,4 . 133,5 = 53,4 ( gam )
=> mZnCl2 = 136 . 0,2 = 27,2 ( gam )
Mdung dịch = Mtham gia - MH2
= 27 + 125 - 0,6 . 2
= 150,8 ( gam )
==> C%AlCl3 = \(\dfrac{53,4}{150,8}\times100\approx35,4\%\)
=> C%ZnCl2 = \(\dfrac{27,2}{150,8}\times100\approx18,04\%\)