a)
\(n_{Fe}=\dfrac{22,4}{56}=0,4\left(mol\right)\)
\(n_{HCl}=\dfrac{18,25}{36,5}=0,5\left(mol\right)\)
PTHH: Fe + 2HCl --> FeCl2 + H2
Xét tỉ lệ: \(\dfrac{0,4}{1}>\dfrac{0,5}{2}\) => Fe dư, HCl hết
PTHH: Fe + 2HCl --> FeCl2 + H2
0,5----------->0,25
=> VH2 = 0,25.22,4 = 5,6 (l)
b)\(n_{Fe_3O_4}=\dfrac{13,92}{232}=0,06\left(mol\right)\)
PTHH: Fe3O4 + 4H2 --to--> 3Fe + 4H2O
Xét tỉ lệ: \(\dfrac{0,06}{1}< \dfrac{0,25}{4}\) => Fe3O4 hết, H2 dư
PTHH: Fe3O4 + 4H2 --to--> 3Fe + 4H2O
0,06-->0,24------->0,18-->0,24
=> \(\left\{{}\begin{matrix}m_{Fe}=0,18.56=10,08\left(g\right)\\m_{H_2O}=0,24.18=4,32\left(g\right)\\m_{H_2\left(dư\right)}=\left(0,25-0,24\right).2=0,02\left(g\right)\end{matrix}\right.\)