mH2SO4= \(\dfrac{180.15}{100}\) = 27 (g) ; mBaCl2= \(\dfrac{320.10}{100}\) = 32 (g)
H2SO4 + BaCl2 ----> BaSO4↓ + 2HCl
--0,3-------0,15----------0,15--------0,3
\(\dfrac{0,3}{1}\)>\(\dfrac{0,15}{1}\) => H2SO4 dư, BaCl2 hết
=> dd sau PU : H2SO4 dư, HCl
nH2SO4 PU = 0,15 mol => nH2SO4 dư = 0,3 - 0,15 = 0,15 mol
mH2SO4 dư = 0,15 . 98 = 14,7 (g) => C% = \(\dfrac{14,7}{180}\) .100= 8,17%
m ↓= 233. 0,15 = 34,95 (g)
-> mdd sau PU = 180 + 320 - 34,95 = 465,05 (g)
mHCl = 0,3 . 36,5 = 10,95 (g) => C%=\(\dfrac{10,95}{465,05}\) .100= 2,35%