mCuSO4= 12,8(g) ->nCuSO4=0,2(mol)
nNa=0,04(mol)
pthh: Na + H2O -> NaOH + 1/2 H2
-> nNaOH= 0,04(mol); nH2=0,02(mol)
=> V(A,đktc)=V(H2,đktc)=0,02.22,4=0,448(l)
2 NaOH + CuSO4 -> Cu(OH)2 + Na2SO4
Ta có: 0,04/2 < 0,2/1
=> CuSO4 dư, NaOH hết, tính theo nNaOH
=> nCu(OH)2=nCuSO4(p.ứ)=nNa2SO4=nNaOH/2=0,02(mol)
=> m(B)=mCu(OH)2=0,02.98=1,96(g)
b) mddC=mddCuSO4 + mNaOH - mCu(OH)2= 400+ 0,04.40- 1,96= 399,64(g)
mCuSO4(dư)= 0,18 x 160=28,8(g)
mNa2SO4=0,02.142= 2,84(g)
=> C%ddCuSO4(dư)= (28,8/399,64).100=7,206%
C%ddNa2SO4=(2,84/399,64).100=0,711%