\(pH=13\Rightarrow\left[H^+\right]=10^{-13}\)
\(\Rightarrow\left[OH^-\right]=10^{-1}\)
\(\Rightarrow n_{OH^-dư}=10^{-1}.0,4=0,04\left(mol\right)\)
\(n_{H^+pư}=a\left(mol\right);n_{OH^-pư}=2b\left(mol\right)\)
\(\Rightarrow0,04+a=2b\Leftrightarrow2b-a=0,04\)