a) \(n_{Fe}=\dfrac{16,8}{56}=0,3\left(mol\right)\)
\(n_S=\dfrac{6,4}{32}=0,2\left(mol\right)\)
\(Fe+S-t^o->FeS\left(1\right)\)
=> A là \(FeS\), \(Fe\left(dư\right)\)
\(Fe+2HCl-->FeCl_2+H_2\uparrow\left(2\right)\)
\(FeS+2HCl-->FeCl_2+H_2S\uparrow\left(3\right)\)
=> B là \(H_2\), \(H_2S\)
\(H_2S+Pb\left(NO_3\right)_2-->PbS+2HNO_3\left(4\right)\)
=> D là \(PbS\)
b) Theo (1) nFe(dư)= 0,3 - 0,2 =0,1(mol)
=> \(n_{H_2\left(2\right)}=0,1\left(mol\right)\)
Theo (1), (3) \(n_{H_2S}=n_{FeS}=0,2\left(mol\right)\)
=> \(V_B=\left(0,1+0,2\right).22,4=6,72\left(l\right)\)
Theo (3), (4) \(n_{PbS}=n_{H_2S}=0,2\left(mol\right)\)
=> mPbS = 0,2.239 = 47,8 (g)
c) \(2H_2+O_2-t^o->2H_2O\left(5\right)\)
\(2H_2S+O_2-t^o->2H_2O+2S\left(6\right)\)
Theo (2), (3), (5), (6)
=> \(V_{O_2}=\left(0,05+0,1\right).22,4=3,36\left(l\right)\)