PTHH:
Phần 1:\(2CO+O_2\rightarrow2CO_2\) (1)
\(2H_2+O_2\rightarrow2H_2O\) (2)
\(CO_2+Ca\left(OH\right)_2\rightarrow CaCO_3\downarrow+H_2O\) (3)
Phần 2: \(CuO+H_2\rightarrow Cu+H_2O\) (4)
\(CuO+CO\rightarrow Cu+CO_2\) (5)
a, Ta có: \(n_{CaCO3}=\dfrac{20}{100}=0,2\left(mol\right)\)
Theo PTHH(3): \(n_{CO2\left(3\right)}=n_{CaCO3}=0,2\left(mol\right)\)
Theo PTHH(1): \(n_{CO2\left(1\right)}=n_{CO2\left(3\right)}=0,2\left(mol\right)\)
Vì 2 phần bằng nhau nên:
\(n_{CO\left(1\right)}=n_{CO\left(5\right)}=0,2\left(mol\right)\)
\(\Rightarrow\)Tổng \(n_{CO}=0,2\cdot2=0,4\left(mol\right)\)
Theo PTHH(5):\(n_{Cu}=n_{CO\left(5\right)}=0,2\left(mol\right)\)
\(\Rightarrow m_{Cu\left(5\right)}=0,2\cdot64=12,8\left(g\right)\)
\(\Rightarrow m_{Cu\left(4\right)}=19,2-12,8=6,4\left(g\right)\)
\(\Rightarrow n_{Cu\left(4\right)}=\dfrac{6,4}{64}=0,1\left(mol\right)\)
Theo PTHH(4): \(n_{H2}=n_{Cu}=0,1\left(mol\right)\)
\(\Rightarrow\)Tổng \(n_{H2}=0,1\cdot2=0,2\left(mol\right)\)
\(\Rightarrow n_{hh}=0,4+0,2=0,6\left(mol\right)\)
\(\Rightarrow V_{hh}=0,6\cdot22,4=13,44\left(l\right)\)
b, Vì tỉ lệ về thể tích cũng là tỉ lệ về số mol nên:
\(\Rightarrow\%V_{CO}=\dfrac{0,2}{0,6}\cdot100\%\approx33,33\%\) \(\%V_{H2}=100\%-33,33\%=66,67\%\)
\(\Rightarrow\%m_{CO}=\dfrac{0,2\cdot28}{0,2\cdot2+0,4\cdot28}\cdot100\%\approx96,55\%\)
\(\%m_{H2}=100\%-96,55\%=3,45\%\)