21. đề sai nha cụ
23. \(n_{Zn}=\dfrac{13}{65}=0,2\left(mol\right)\)
\(n_{CuCl_2}=\dfrac{67,5.60\%}{135}=0,3\left(mol\right)\)
Pt: \(Zn+CuCl_2\rightarrow ZnCl_2+Cu\)
0,2 mol 0,3mol \(\rightarrow\) 0,2mol \(\rightarrow\)0,2mol
Lập tỉ số: \(n_{Zn}:n_{CuCl_2}=0,2< 0,3\)
Zn hết, CuCl2 dư
\(m_{Cu}=0,2.64=12,8\left(g\right)\)
\(\Sigma_{m\left(spu\right)}=13+67,5-12,8=67,7\left(g\right)\)
\(C\%_{CuCl_2\left(dư\right)}=\dfrac{\left(0,3-0,2\right).135}{67,6}.100=19,94\%\)
\(C\%_{ZnCl_2}=\dfrac{0,2.136}{67,7}.100=40,18\%\)