\(n_{Fe}=\dfrac{12.6}{56}=0.225\left(mol\right)\)

\(n_{O_2}=\dfrac{4.2}{22.4}=0.1875\left(mol\right)\)

\(3Fe+2O_2\underrightarrow{^{^{t^0}}}Fe_3O_4\)

\(3.........2\)

\(0.225......0.1875\)

Lập tỉ lệ : \(\dfrac{0.225}{3}< \dfrac{0.1875}{2}\Rightarrow O_2dư\)

\(m_{O_2\left(dư\right)}=\left(0.1875-0.225\cdot\dfrac{2}{3}\right)\cdot32=1.2\left(g\right)\)

\(m_{Fe_3O_4}=\dfrac{0.225}{3}\cdot232=17.4\left(g\right)\)

\(n_P = \dfrac{6,2}{31} = 0,2(mol)\\ n_{O_2} = \dfrac{6,72}{22,4} = 0,3(mol)\\ \dfrac{n_P}{4} = 0,05 < \dfrac{n_{O_2}}{5} = 0,06\)

Do đó : O₂ dư.

4P       +        5O₂        \(\xrightarrow{t^o} \)  2P₂O₅

0,2..............0,25..................0,1..................(mol)

\(n_{O_2\ dư} = 0,3 - 0,25 = 0,05(mol)\)

\(m_{P_2O_5} = 0,1.142 = 14,2(gam)\)

Bài 1:

PT: \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)

a, Ta có: \(n_{Fe}=\dfrac{5,6}{56}=0,1\left(mol\right)\)

\(n_{O_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)

Xét tỉ lệ: \(\dfrac{0,1}{3}< \dfrac{0,1}{2}\), ta được O₂ dư.

Theo PT: \(n_{O_2\left(pư\right)}=\dfrac{2}{3}n_{Fe}=\dfrac{1}{15}\left(mol\right)\)

\(\Rightarrow n_{O_2\left(dư\right)}=0,1-\dfrac{1}{15}=\dfrac{1}{30}\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}m_{O_2\left(dư\right)}=\dfrac{1}{30}.32\approx1,067\left(g\right)\\V_{O_2\left(dư\right)}=\dfrac{1}{30}.2,24\approx0,746\left(l\right)\end{matrix}\right.\)

b, Theo PT: \(n_{Fe_3O_4}=\dfrac{1}{3}n_{Fe}=\dfrac{1}{30}\left(mol\right)\)

\(\Rightarrow m_{Fe_3O_4}=\dfrac{1}{30}.232\approx7,733\left(g\right)\)

Bài 2:

PT: \(3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\)

a, Ta có: \(n_{Fe}=\dfrac{11,2}{56}=0,2\left(mol\right)\)

Theo PT: \(n_{Fe_3O_4}=\dfrac{1}{3}n_{Fe}=\dfrac{1}{15}\left(mol\right)\)

\(\Rightarrow m_{Fe_3O_4}=\dfrac{1}{15}.232\approx15,467\left(g\right)\)

b, Theo PT: \(n_{O_2}=\dfrac{2}{3}n_{Fe}=\dfrac{2}{15}\left(mol\right)\)

\(\Rightarrow V_{O_2}=\dfrac{2}{15}.22,4\approx2,9867\left(l\right)\)

c, PT: \(2N_2+5O_2\underrightarrow{t^o}2N_2O_5\)

Ta có: \(n_{N_2}=\dfrac{2,8}{28}=0,1\left(mol\right)\)

Xét tỉ lệ: \(\dfrac{0,1}{2}>\dfrac{\dfrac{2}{15}}{5}\), ta được N₂ dư.

Theo PT: \(n_{N_2O_5}=\dfrac{2}{5}n_{O_2}=\dfrac{4}{75}\left(mol\right)\)

\(\Rightarrow m_{N_2O_5}=\dfrac{4}{75}.108=5,76\left(g\right)\)

Bạn tham khảo nhé!

Bài 1 : 

\(n_{Fe}=\dfrac{5.6}{56}=0.1\left(mol\right)\)

\(n_{O_2}=\dfrac{2.24}{224}=0.1\left(mol\right)\)

     \(3Fe+2O_2\underrightarrow{t^0}Fe_3O_4\)

\(Bđ:0.1......0.1\)

\(Pư:0.1.......\dfrac{1}{15}...\dfrac{1}{30}\)

\(Kt:0........\dfrac{1}{30}....\dfrac{1}{30}\)

\(V_{O_2\left(dư\right)}=\dfrac{1}{30}\cdot22.4=0.747\left(l\right)\)

\(m_{Fe_3O_4}=\dfrac{1}{30}\cdot232=7.73\left(g\right)\)

Bài 2 : 

\(n_{Fe}=\dfrac{11.2}{56}=0.2\left(mol\right)\)

\(3Fe+2O_2\underrightarrow{t^0}Fe_3O_4\)

\(0.2.......0.3.......\dfrac{1}{15}\)

\(V_{O_2}=0.3\cdot22.4=6.72\left(l\right)\)

\(m_{Fe_3O_4}=\dfrac{1}{15}\cdot232=15.47\left(g\right)\)

\(n_{N_2}=\dfrac{2.8}{28}=0.1\left(mol\right)\)

\(2N_2+5O_2\underrightarrow{t^0}2N_2O_5\)

\(0.12......0.3........0.12\)

\(m_{N_2O_5}=0.12\cdot108=12.96\left(g\right)\)

nCu = 12.8/64 = 0.2 mol 

nO2 = 11.2/22.4 = 0.5 (mol) 

Cu + 1/2O2 -to-> CuO 

0.2____0.1______0.2

m O2 dư = ( 0.5 - 0.1 ) * 32 = 12.8 (g) 

mCuO = 0.2*80=16 (g) 

Ta có PTHH:

                                                \(2Cu+O_2\rightarrow2CuO\)

Ta có số mol của các chất : 

\(n_{Cu}=\frac{m_{Cu}}{M_{Cu}}=\frac{12,8}{64}=0,2\left(mol\right)\)

\(n_{O_2}=\frac{V_{O_2}}{22,4}=\frac{11,2}{22,4}=0,5\left(mol\right)\)

\(\Rightarrow\frac{n_{Cu}}{2}=\frac{0,2}{2}< \frac{0,5}{1}=\frac{n_{O_2}}{1}\)

\(\Rightarrow\)Cu hết, O₂ dư

\(\Rightarrow\)Tính theo Cu

Ta viết lại PTHH theo tỉ số các chất ;

                                      \(2Cu+O_2\rightarrow2CuO\)

           Ban đầu:             \(0,2\)   \(0,5\)     \(0\)

          Phản ứng:           \(0,2\)    \(0,1\)   \(0,2\)

          Sau phản ứng:      \(0\)      \(0,4\)   \(0,2\)

\(\Rightarrow\)Khối lượng chất tạo thành là :

        \(m_{CuO}=n_{CuO}.M_{CuO}=0,2.80=16\left(g\right)\)

nP= 7,44/31=0,24(mol)

nO2=6,16/22,4=0,275(mol)

PTHH:4 P + 5 O2 -to->2  P2O5

Ta có: 0,24/4 > 0,275/5

=> O2 hết, P dư, tính theo nO2

nP(p.ứ)= 0,275 x 4/5= 0,22(mol)

=>nP(dư)=0,24-0,22=0,02(mol)

=>mP(dư)=0,02.31= 0,62(g)

nP2O5= 2/5 x 0,275= 0,11(mol)

=> mP2O5= 142 x 0,11= 15,62(g)

\(n_P=\dfrac{7,44}{31}=0,24\left(mol\right)\)

\(n_{O_2}=\dfrac{6,16}{22,4}=0,275\left(mol\right)\)

PTHH :                       \(4P+5O_2\rightarrow2P_2O_5\)

Ban đầu :                0,24    0,275                   (mol)

Phản ứng :             0,22    0,275       0,11    (mol)

Sau phản ứng :      0,02      0            0,11    (mol)

\(m_P=0,02.31=0,62\left(g\right)\)

\(m_{P_2O_5}=0,11.142=15,62\left(g\right)\) 

\(n_P=\dfrac{6.2}{31}=0.2\left(mol\right)\)

\(n_{O_2}=\dfrac{8.96}{22.4}=0.4\left(mol\right)\)

\(4P+5O_2\underrightarrow{^{^{t^0}}}2P_2O_5\)

\(4........5\)

\(0.2.........0.4\)

Lập tỉ lệ : \(\dfrac{0.2}{4}< \dfrac{0.4}{5}\Rightarrow O_2dư\)

\(n_{P_2O_5}=0.2\cdot\dfrac{2}{4}=0.1\left(mol\right)\)

\(m_{P_2O_5}=0.1\cdot142=14.2\left(g\right)\)

\(m_{P_2O_5\left(tt\right)}=14.2\cdot80\%=11.36\left(g\right)\)

nP = 3,1/31 = 0,1 (mol)

PTHH: 4P + 5O2 -t°-> 2P2O5

             0,1---> 0,125--->0,05

VO2 = 0,125 . 22,4 = 2,8 (l)

mP2O5 = 0,05 . 142 = 7,1 (g)

\(n_P=\dfrac{3,1}{31}=0,1mol\)

\(4P+5O_2\underrightarrow{t^o}2P_2O_5\)

0,1     0,125   0,05

\(V_{O_2}=0,125\cdot22,4=2,8l\)  

\(m_{P_2O_5}=0,05\cdot142=7,1g\)

a,PTHH : \(4P+5O_2->2P_2O_5\)

b, 

Số mol O2 tham gia phản ứng :

nO2 = 5/4.n_P = 5/4 . 0,1 = 0,125 ( mol )

=> V O₂ phản ứng : 0,125 . 22,4 = 2,8 ( lít )

c,

Số mol P2O5 : n_p2o5 = 1/2.n_p = 0,05 ( mol )

=> m = 142 . 0,05 = 7,1 (g)

\(n_{Al}=\dfrac{m}{M}=\dfrac{10,8}{27}=0,4\left(mol\right)\\ a.PTHH:4Al+3O_2\underrightarrow{t^o}2Al_2O_3\) 

                    4         3            2

                   0,4      0,3         0,2

\(m_{Al_2O_3}=n.M=0,2.\left(27.2+16.3\right)=20,4\left(g\right)\\ c.V_{O_2}=n.24,79=0,3.24,79=7,437\left(l\right)\) 

\(d.n_{O_2}=\dfrac{m}{M}=\dfrac{12,8}{\left(16.2\right)}=0,4\left(mol\right)\\ PTHH:4Al+3O_2\underrightarrow{t^o}2Al_2O_3\) 

                 4         3          2

              0,53      0,4      0,27

Tỉ lệ: \(\dfrac{0,53}{4}< \dfrac{0,4}{3}< \dfrac{0,27}{2}\Rightarrow Al_2O_3\) dư và dư \(m_{Al_2O_3}=n.M=0,27.\left(27.2+16.3\right)=27,54\left(g\right).\)

a, \(4Al+3O_2\underrightarrow{t^o}2Al_2O_3\)

b, \(n_{Al}=\dfrac{10,8}{27}=0,4\left(mol\right)\)

Theo PT: \(n_{Al_2O_3}=\dfrac{1}{2}n_{Al}=0,2\left(mol\right)\Rightarrow m_{Al_2O_3}=0,2.102=20,4\left(g\right)\)

c, \(n_{O_2}=\dfrac{3}{4}n_{Al}=0,3\left(mol\right)\Rightarrow V_{O_2}=0,3.22,4=6,72\left(l\right)\)

d, \(n_{O_2}=\dfrac{12,8}{32}=0,4\left(mol\right)\)

Xét tỉ lệ: \(\dfrac{0,4}{4}< \dfrac{0,4}{3}\), ta được O₂ dư.

\(\Rightarrow n_{O_2\left(dư\right)}=0,4-0,3=0,1\left(mol\right)\Rightarrow m_{O_2\left(dư\right)}=0,1.32=3,2\left(g\right)\)