Chọn A

Để đạt V lớn nhất thì sẽ xảy ra trường hợp tạo kết tủa sau đó kết tủa tan 1 phần.

OH- + H+ → H2O

[Al(OH)4]-  + H+ →  Al(OH)3 ↓ +  H2O Al(OH)3      + 3H+ →  Al3+   + 3H2O

 nH+ = nOH- + 4nAlO2- - 3nAl(OH)3    = 0,3.0,6 + 4.0,3.1- 3.      = 0,78 mol

 → VHCl = 390 ml

1) \(n_{Al\left(OH\right)_3}=\dfrac{0,78}{78}=0,01\left(mol\right)\)

PTHH: \(Al_2\left(SO_4\right)_3+6NaOH\rightarrow3Na_2SO_4+2Al\left(OH\right)_3\) 

                                   0,03<----------------------0,01

=> n_{NaOH min} = 0,03 (mol)

=> \(C_{M\left(NaOH\right)}=\dfrac{0,03}{0,2}=0,15M\)

2) \(n_{Al_2O_3}=\dfrac{5,1}{102}=0,05\left(mol\right)\)

\(n_{Al_2\left(SO_4\right)_3}=0,3.0,25=0,075\left(mol\right)\)

PTHH: \(6NaOH+Al_2\left(SO_4\right)_3\rightarrow3Na_2SO_4+2Al\left(OH\right)_3\)

           0,45<------0,075-------------------------->0,15

            \(NaOH+Al\left(OH\right)_3\rightarrow NaAlO_2+2H_2O\)

             0,05<----0,05

            \(2Al\left(OH\right)_3\underrightarrow{t^o}Al_2O_3+3H_2O\)

              0,1<-------0,05

=> n_{NaOH max} = 0,5 (mol)

=> \(V_{dd}=\dfrac{0,5}{2}=0,25\left(l\right)=250\left(ml\right)\)

3)

\(n_{KOH\left(1\right)}=0,15.1,2=0,18\left(mol\right)\)

\(n_{Al\left(OH\right)_3\left(1\right)}=\dfrac{4,68}{78}=0,06\left(mol\right)\)

\(n_{AlCl_3}=0,1.x\left(mol\right)\)

Do khi cho KOH tác dụng với dd Y xuất hiện kết tủa

=> Trong Y chứa AlCl₃ dư

PTHH: \(3KOH+AlCl_3\rightarrow3KCl+Al\left(OH\right)_3\)

           0,18---->0,06----------------->0,06

\(n_{KOH\left(2\right)}=0,175.1,2=0,21\left(mol\right)\)

\(n_{Al\left(OH\right)_3\left(2\right)}=\dfrac{2,34}{78}=0,03\left(mol\right)\)

PTHH: \(3KOH+AlCl_3\rightarrow3KCl+Al\left(OH\right)_3\)

   (0,3x-0,18)<--(0,1x-0,06)------->(0,1x-0,06)

            \(KOH+Al\left(OH\right)_3\rightarrow KAlO_2+2H_2O\)

     (0,1x-0,09)<-(0,1x-0,09)

=> \(\left(0,3x-0,18\right)+\left(0,1x-0,09\right)=0,21\)

=> x = 1,2

Ta có: \(n_{HCl}=\dfrac{200}{1000}.2=0,4\left(mol\right)\)

\(PTHH:Mg+2HCl--->MgCl_2+H_2\uparrow\left(1\right)\)

a. Theo PT₍₁₎: \(n_{Mg}=n_{H_2}=n_{MgCl_2}=\dfrac{1}{2}.n_{HCl}=\dfrac{1}{2}.0,4=0,2\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}m_{Mg}=0,2.24=4,8\left(g\right)\\V_{H_2}=0,2.22,4=4,48\left(lít\right)\end{matrix}\right.\)

b. \(PTHH:2NaOH+MgCl_2--->Mg\left(OH\right)_2\downarrow+2NaCl\left(2\right)\)

Ta có: \(n_{NaOH}=\dfrac{\dfrac{20\%.100}{100\%}}{40}=0,5\left(mol\right)\)

Ta thấy: \(\dfrac{0,5}{2}>\dfrac{0,2}{1}\)

Vậy NaOH dư.

Theo PT₍₂₎: \(n_{Mg\left(OH\right)_2}=n_{MgCl_2}=0,2\left(mol\right)\)

\(\Rightarrow m_{Mg\left(OH\right)_2}=0,2.58=11,6\left(g\right)\)

a: \(Mg+2HCl\rightarrow MgCl_2+H_2\)

200ml=0,2 lít

\(n_{HCl}=0.2\cdot22.4=4.48\left(mol\right)\)

\(\Leftrightarrow n_{H_2}=2.24\left(mol\right)\)

\(\Leftrightarrow m_{H_2}=n_{H_2}\cdot M=2.24\cdot1=2.24\left(g\right)\)

\(n_{MgCl_2}=2.24\left(mol\right)\)

\(\Leftrightarrow n_{Mg}=2.24\left(mol\right)\)

\(\Leftrightarrow m_{Mg}=2.24\cdot24=53.76\left(g\right)\)

\(n_{NaOH}=0,1.3=0,3mol\\ n_{Al\left(OH\right)_3}=\dfrac{7,02}{78}=0,09mol\\ \dfrac{1}{3}n_{NaOH}>n_{Al\left(OH\right)_3}\Rightarrow NaOH\left(dư\right)\)

\(3NaOH+AlCl_3\rightarrow3NaCl+Al\left(OH\right)_3\)

0,27          0,09        0,09             0,27

\(V_{AlCl_3}=\dfrac{0,09}{2}=0,045l\)

Đáp án cần chọn là: C

Đáp án cần chọn là: C