Câu 1:

\(m_{CaO(\text {phản ứng})}=\dfrac{50,4}{90\%}=56(g)\\ \Rightarrow n_{CaO}=\dfrac{56}{56}=1(mol)\\ PTHH:CaCO_3\xrightarrow{t^o}CaO+CO_2\\ \Rightarrow n_{CaCO_3}=1(mol)\\ \Rightarrow m_{CaCO_3}=100.1=100(g)\\ \Rightarrow m_{\text {đá vôi}}=\dfrac{100}{90\%}\approx 111,11(g)\)

nKNO3 = 0.2 (mol) 

2KNO3 -to-> 2KNO2 + O2 

0.2__________0.2____0.1 

mKNO2 = 0.2*85=17(g) 

C + O2 -to-> CO2 

x___x

S + O2 -to-> SO2 

y___y

x + y = 0.1 (1) 

Mặt khác : 

+) 32y/m * 100% = 4% 

=> 32y = 0.04m (2) 

+) 12x/m = 0.92 

=> 12x = 0.92m (3) 

(1) , (2) , (3) : 

x = 0.1 

y = 0.002

m = 1.3 

VCO2 + VSO2 = ( 0.1 + 0.002) * 22.4 = 2.2848 (l) 

Đáp án D

ĐÁP ÁN  D

M = 15,75; n_X = 48 kmol;

C + H₂O -> CO + H₂     C + 2H₂O -> CO₂ + 2H₂

x--------------x------x         y----------------y------2y        kmol

Hỗn hợp X gồm x mol CO ; (x + 2y) mol H₂ ; y mol CO₂     

Ta có : n_X = 2x + 3y = 48; m_X = 30x + 48y =756;

=> x = 6 ; y = 12;

=> m =18.12/(0,96.0,96) = 234,375 kg

Khối lượng C chứa trong 1 tấn than:

PTHH: \(C+O_2\xrightarrow[]{t^o}CO_2\)

           12---32-------gam

           0,96--x-------tấn

\(\Rightarrow x=\dfrac{0,96.32}{12}=2,56\left(\text{tấn}\right)\)

Ta có: \(m_C=1,5.1000.90\%=1350\left(g\right)\)

\(n_C=\dfrac{1350}{12}=112,5\left(mol\right)\)

PT: \(C+O_2\underrightarrow{t^o}CO_2\)

Theo PT: \(n_{O_2}=n_C=112,5\left(mol\right)\)

\(\Rightarrow V_{O_2}=112,5.22,4=2520\left(l\right)\)

\(V_{kk}=V_{O_2}.5=12600\left(l\right)\)

a,PTHH: C   +  O2  ->  CO2   (*)

            x        x             x    (mol)

           S  +  O2  ->  SO2     (**)

           y       y            y      (mol)

Ta có dB/H2=9 => MB = 29.2=58 (g)=m hh khí B / n hh Khí B

<=>58= \(\frac{44x+64y}{x+y}\)

=>44x+64y=58x+58y

<=>7x=3y

<=> 7x-3y=0   (1)

Mà hh A =12x+32y=13 (2)

b,Từ (1),(2) ta có hệ pt

\(\hept{\begin{cases}7x-3y=0\\12x+3y=13\end{cases}}\Leftrightarrow\hept{\begin{cases}x=0,15\\y=0,35\end{cases}}\)

=>%C = (12.0,15)/13 .100%=13,84%

    %S= 100%-13,84%= 86,16%

Từ pt (*),(**) ta có VO2(đktc)=(x+y).22,4=11,2(l)

\(a.\)

\(GS:\)

\(n_{hh}=1\left(mol\right)\)

\(Đặt:n_{N_2}=a\left(mol\right),n_{CO_2}=b\left(mol\right)\)

\(\Rightarrow a+b=1\left(1\right)\)

\(m_A=28a+44b=18\cdot2=36\left(2\right)\)

\(\left(1\right),\left(2\right):\)

\(a=b=0.5\)

\(\%m_{N_2}=\dfrac{0.5\cdot28}{0.5\cdot28+0.5\cdot44}\cdot100\%=38.89\%\)

\(\%m_{CO_2}=61.11\%\)

\(b.\)

\(\dfrac{n_{N_2}}{n_{CO_2}}=\dfrac{0.5}{0.5}=\dfrac{1}{1}\)

\(n_{N_2}=n_{CO_2}=\dfrac{1}{2}\cdot n_A=\dfrac{0.2}{2}=0.1\left(mol\right)\)

\(Đặt:n_{CO_2}=x\left(mol\right)\)

\(\overline{M}=\dfrac{0.1\cdot28+0.1\cdot44+44x}{0.2+x}=20\cdot2=40\left(\dfrac{g}{mol}\right)\)

\(\Rightarrow x=0.2\)

\(m_{CO_2\left(cầnthêm\right)}=0.2\cdot44=8.8\left(g\right)\)