PTHH: Fe + 2HCl --> FeCl₂ + H₂

            FeS + 2HCl --> FeCl₂ + H₂S

=> \(n_{Fe}+n_{FeS}=n_{H_2}+n_{H_2S}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\)

Và 56.n_Fe + 88.n_FeS = 18,8

=> \(\left\{{}\begin{matrix}n_{Fe}=0,1\left(mol\right)\\n_{FeS}=0,15\left(mol\right)\end{matrix}\right.\)

Bảo toàn S: n_CaSO3 = 0,15 (mol)

=> m = 0,15.120 = 18 (g)

=> B

B

Ta có: \(n_{CH_4}+n_{C_2H_2}=\dfrac{1,68}{22,4}=0,075\left(mol\right)\left(1\right)\)

PT: \(CH_4+2O_2\underrightarrow{t^o}CO_2+2H_2O\)

\(2C_2H_2+5O_2\underrightarrow{t^o}4CO_2+2H_2O\)

\(CO_2+Ca\left(OH\right)_2\rightarrow CaCO_{3\downarrow}+H_2O\)

Theo PT: \(n_{CaCO_3}=n_{CO_2}=n_{CH_4}+2n_{C_2H_2}=\dfrac{10}{100}=0,1\left(mol\right)\left(2\right)\)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{CH_4}=0,05\left(mol\right)\\n_{C_2H_2}=0,025\left(mol\right)\end{matrix}\right.\Rightarrow\left\{{}\begin{matrix}V_{CH_4}=0,05.22,4=1,12\left(l\right)\\V_{C_2H_2}=0,025.22,4=0,56\left(l\right)\end{matrix}\right.\)

\(Đặt:n_{CH_4}=a\left(mol\right),n_{C_2H_2}=b\left(mol\right)\)

\(n_{hh}=a+b=0.35\left(mol\right)\left(1\right)\)

\(BTC:\)

\(a+2b=0.6\)

\(a=1\)

\(b=0.25\)

\(\%CH_4=\dfrac{0.1}{0.35}\cdot100\%=28.57\%\)

\(\%C_2H_2=71.43\%\)

\(\left\{{}\begin{matrix}n_{CH_4}=x\left(mol\right)\\n_{C_2H_2}=y\left(mol\right)\end{matrix}\right.\)⇒ x + y = \(\dfrac{7,84}{22,4} = 0,35(mol)\)

\(CH_4 + 2O_2 \xrightarrow{t^o} CO_2 + 2H_2O\\ C_2H_2 + \dfrac{5}{2}O_2 \xrightarrow{t^o} 2CO_2 + H_2O\\ CO_2 + Ca(OH)_2 \to CaCO_3 + H_2O\)

Theo PTHH : x + 2y = \(\dfrac{60}{100} = 0,6(2)\)

Từ (1)(2) suy ra x = 0,1 ; y = 0,25

Vậy : 

\(\%V_{CH_4} = \dfrac{0,1}{0,35}.100\% = 28,57\%\\ \%V_{C_2H_2} = 100\% - 28,57\% = 71,43\%\)

Chọn A

\(n_{C_2H_4}=\dfrac{4.48}{22.4}=0.2\left(mol\right)\)

\(C_2H_4+3O_2\underrightarrow{^{t^0}}2CO_2+2H_2O\)

\(0.2.........0.6........0.4..........0.4\)

\(V_{O_2}=0.6\cdot22.4=13.44\left(l\right)\)

\(m_{H_2O}=0.4\cdot18=7.2\left(g\right)\)

\(Ca\left(OH\right)_2+CO_2\rightarrow CaCO_3+H_2O\)

\(..............0.4.....0.4\)

\(m_{CaCO_3}=0.4\cdot100=40\left(g\right)\)

Gọi \(\left\{{}\begin{matrix}n_{CO}=a\left(mol\right)\\n_{CH_4}=b\left(mol\right)\end{matrix}\right.\Rightarrow28a+16b=2,04\left(1\right)\)

\(n_{CaCO_3}=\dfrac{9,6}{100}=0,096\left(mol\right)\)

PTHH: \(2CO+O_2\xrightarrow[]{t^o}2CO_2\)

               a------------>a

             \(CH_4+2O_2\xrightarrow[]{t^o}CO_2+2H_2O\)

               b---------------->b

            \(Ca\left(OH\right)_2+CO_2\rightarrow CaCO_3\downarrow+H_2O\)

                                0,096<--0,096

`=> a + b = 0,096 (2)`

`(1), (2) => a = 0,042; b = 0,054`

\(\Rightarrow\left\{{}\begin{matrix}\%V_{CO}=\dfrac{0,042}{0,042+0,054}.100\%=43,75\%\\\%V_{CH_4}=100\%-43,75\%=56,25\%\end{matrix}\right.\)

a) 

Gọi số mol C₂H₅OH, CH₃COOH là a, b (mol)

\(n_{O_2}=\dfrac{11,2}{22,4}=0,5\left(mol\right)\); \(n_{CaCO_3}=\dfrac{40}{100}=0,4\left(mol\right)\)

PTHH: C₂H₅OH + 3O₂ --t^o--> 2CO₂ + 3H₂O

                  a----->3a-------->2a

            CH₃COOH + 2O₂ --t^o--> 2CO₂ + 2H₂O

                    b------>2b-------->2b

            Ca(OH)₂ + CO₂ --> CaCO₃ + H₂O

                               0,4<----0,4

=> \(\left\{{}\begin{matrix}3a+2b=0,5\\2a+2b=0,4\end{matrix}\right.\) => a = 0,1 (mol); b = 0,1 (mol)

a = 0,1.46 + 0,1.60 = 10,6 (g) 

b) \(\left\{{}\begin{matrix}\%m_{C_2H_5OH}=\dfrac{0,1.46}{10,6}.100\%=43,4\%\\\%m_{CH_3COOH}=\dfrac{0,1.60}{10,6}.100\%=56,6\%\end{matrix}\right.\)

c)

PTHH: 2CH₃COOH + Na₂CO₃ --> 2CH₃COONa + CO₂ + H₂O

                   0,1----------------------------------->0,05

B là khí CO₂

V = 0,05.22,4 = 1,12 (l)

Đáp án B

Ta có: