\(m_{ct}=\dfrac{5.200}{100}=10\left(g\right)\)

\(n_{NaOH}=\dfrac{10}{40}=0,25\left(mol\right)\)

Pt : \(NaOH+HCl\rightarrow NaCl+H_2O|\)

           1             1             1         1

        0,25          0,25        0,25

a) \(n_{HCl}=\dfrac{0,25.1}{1}=0,25\left(mol\right)\)

\(m_{HCl}=0,25.36,5=9,125\left(g\right)\)

\(m_{ddHCl}=\dfrac{9,125.100}{3,65}=250\left(g\right)\)

b) \(n_{NaCl}=\dfrac{0,25.1}{1}=0,25\left(mol\right)\)

⇒ \(m_{NaCl}=0,25.58,5=14,625\left(g\right)\)

\(m_{ddspu}=200+250=450\left(g\right)\)

\(C_{NaCl}=\dfrac{14,625.100}{450}=3,25\)⁰/₀

 Chúc bạn học tốt

a) \(n_{NaOH}=\dfrac{200.5\%}{40}=0,25\left(mol\right)\)

PTHH: NaOH + HCl → NaCl + H₂O

Mol:       0,25      0,25    0,25

\(m_{ddHCl}=\dfrac{0,25.36,5.100}{3,65}=250\left(g\right)\)

b) m_{dd sau pứ} = 200 + 250 = 450 (g)

\(C\%_{ddNaCl}=\dfrac{0,25.58,5.100\%}{450}=3,25\%\)

a) $NaOH + HCl \to NaCl + H_2O$

$n_{HCl} = n_{NaOH} = \dfrac{200.5\%}{40} = 0,25(mol)$

$\Rightarrow n_{HCl} = \dfrac{0,25.36,5}{3,65\%} = 250(gam)$

b)

$m_{dd\ sau\ pư} = 200 + 250 = 450(gam)$
$C\%_{NaCl} = \dfrac{0,25.58,5}{450}.100\% = 3,25\%$

1.

\(Mg+H_2SO_4-->MgSO_4+H_2\)

\(MgSO_4+2NaOH-->Mg\left(OH\right)_2+Na_2SO_4\)

\(Mg\left(OH\right)_2-->MgO+H_2O\)

\(MgO+2HCl-->MgCl_2+H_2O\)

2. \(n_{HCl}=\dfrac{200\cdot18,25}{100.36,5}=1\left(mol\right)\)

a) PTHH : \(Ca\left(OH\right)_2+2HCl-->CaCl_2+2H_2O\)

Theo pthh : \(n_{Ca\left(OH\right)2}=\dfrac{1}{2}n_{HCl}=0,5\left(mol\right)\)

=> \(m_{ddCa\left(OH\right)2}=\dfrac{74.0,5\cdot100}{10}=370\left(g\right)\)

b) Theo pthh : \(n_{CaCl_2}=n_{Ca\left(OH\right)2}=0,5\left(mol\right)\)

=> \(m_{CaCl2}=55,5\left(g\right)\)

Áp dụng DDLBTKL :

m_{(dd Ca(oh)2)} + m_(ddHCl) = m_(ddCaCl2)

=> 370 + 200 = 570 g

=> \(C\%CaCl_2=\dfrac{55,5}{570}\cdot100\%=9,74\%\)

Coi $m_{dd\ HCl} = 100(gam) \Rightarrow n_{HCl} = \dfrac{100.7,3\%}{36,5} = 0,2(mol)$
Gọi $n_{BaCO_3} = a(mol)$

BaCO₃  +   2HCl  →  BaCl₂  +  CO₂  + H₂O

a..................2a............a..............a........................(mol)

Sau phản ứng : 

$m_{dd} = 197a + 100 - a.44 = 153a + 100(gam)$
$n_{HCl\ dư} = 0,2 - 2a(mol)$

Suy ra : 

$C\%_{HCl} = \dfrac{(0,2-2a).36,5}{153a + 100}.100\% = 2,28\%$

$\Rightarrow a = 0,066$

$C\%_{BaCl_2} = \dfrac{0,066.208}{0,066.153 + 100}.100\% = 12,47\%$

a, \(m_{CH_3COOH}=20.3,75\%=0,75\left(g\right)\Rightarrow n_{CH_3COOH}=\dfrac{0,75}{60}=0,0125\left(mol\right)\)

PT: \(2CH_3COOH+Ca\left(OH\right)_2\rightarrow\left(CH_3COO\right)_2Ca+2H_2O\)

Theo PT: \(n_{Ca\left(OH\right)_2}=\dfrac{1}{2}n_{CH_3COOH}=0,00625\left(mol\right)\)

\(\Rightarrow V_{ddCa\left(OH\right)_2}=\dfrac{0,00625}{0,2}=0,03125\left(l\right)=31,25\left(ml\right)\)

b, \(n_{\left(CH_3COO\right)_2Ca}=\dfrac{1}{2}n_{CH_3COOH}=0,00625\left(mol\right)\)

\(\Rightarrow m_{\left(CH_3COO\right)_2Ca}=0,00625.158=0,9875\left(g\right)\)

\(n_{SO_2}= \dfrac{7,84}{22,4}=0,35 mol\)

\(n_{Ca(OH)_2}= 0,2 . 1,4=0,28mol\)

Ta có:

\(T=\dfrac{n_{nhóm OH}}{n_{SO_2}}\)\(=\dfrac{2. 0,28}{0,35}= 1,6\)

Có: 1<T<2

Nên Phản ứng tạo hỗn hợp 2 muối trung hòa và axit

\(Ca(OH)_2 + SO_2 \rightarrow CaSO_3 + H_2O\) (1)

\(CaSO_3 + SO_2 + H_2O \rightarrow Ca(HSO_3)_2\) (2)

Theo PTHH (1):

\(n_{SO_2(1)}\)\(n_{CaSO_3} = n_{Ca(OH)_2}= 0,28mol\)

\(\Rightarrow n_{SO_2(2)}=0,35 - 0,28= 0,07 mol\)

Theo PTHH (2):

\(n_{CaSO_3bị hòa tan}\)\(=\)\(n_{Ca(HSO_3)_2}= n_{SO_2(2)}= 0,07 mol\)

Suy ra: \(n_{CaSO_3 sau pư}= 0,28 - 0,07= 0,21 mol\)

\(m_{muối}= m_{CaSO_3} + m_{Ca(HSO_3)_2}= 0,21 .120 + 0,07 . 202= 39,34g\)

b)

\(C_{M Ca(HSO_3)_2}= \dfrac{0,07}{0,2}= 0,35M\)

Tiếp của NaOH nhé:

PTHH:

SO₂ + Ca(OH)₂ ---> CaSO₃ + H₂O (1)

2SO₂ + Ca(OH)₂ ---> Ca(HSO₃)₂

a. Gọi x, y lần lượt là số mol của CaSO₃ và Ca(HSO₃)₂

Theo PT₍₁₎: \(n_{SO_2}=n_{Ca\left(OH\right)_2}=n_{CaSO_3}=x\left(mol\right)\)

Theo PT₍₂₎: \(n_{SO_2}=2.n_{Ca\left(HSO_3\right)_2}=2y\left(mol\right)\)

Theo PT₍₂₎: \(n_{Ca\left(OH\right)_2}=n_{Ca\left(HSO_3\right)_2}=y\left(mol\right)\)

Vậy ta được:

\(\left\{{}\begin{matrix}x+2y=0,35\\x+y=0,28\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,21\\y=0,07\end{matrix}\right.\)

=> \(m_{CaSO_3}=0,21.120=25,2\left(g\right)\) 

b. Ta có: \(V_{dd_{Ca\left(OH\right)_2}}=V_{dd_{thu.được}}=\dfrac{200}{1000}=0,2\left(mol\right)\)

\(C_{M_{Ca\left(HSO_3\right)_2}}=\dfrac{0,07}{0,2}=0,35M\)

\(GS:m_{dd_{HCl}}=100\left(g\right)\)

\(m_{HCl}=100\cdot7.3\%=7.3\left(g\right)\)

\(n_{BaCO_3}=a\left(mol\right)\)

\(BaCO_3+2HCl\rightarrow BaCl_2+CO_2+H_2O\)

\(a..........2a.........a......a\)

\(m_{\text{dung dịch sau phản ứng}}=197a+100-44a=153a+100\left(g\right)\)\(\)

\(m_{HCl}=7.3-73a\left(g\right)\)

\(C\%_{HCl\left(dư\right)}=\dfrac{7.3-73a}{153a+100}\cdot100\%=2.28\%\)

\(\Rightarrow a=0.065\)

\(C\%_{BaCl_2}=\dfrac{0.065\cdot208}{153\cdot0.065+100}\cdot100\%=12.3\%\)

\(a.n_{CO_2}=\dfrac{0,672}{22,4}=0,03mol\\ CO_2+Ca\left(OH\right)_2\rightarrow CaCO_3+H_2O\)

\(n_{CO_2}=n_{Ca\left(OH\right)_2}=n_{CaCO_3}=0,03mol\\ m_{CaCO_3}=0,03.100=3g\\ b.V_{ddCa\left(OH\right)_2}=\dfrac{0,03}{1,5}=0,02l\)

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