Coi $m_{dd\ HCl} = 100(gam) \Rightarrow n_{HCl} = \dfrac{100.7,3\%}{36,5} = 0,2(mol)$
Gọi $n_{BaCO_3} = a(mol)$
BaCO3 + 2HCl → BaCl2 + CO2 + H2O
a..................2a............a..............a........................(mol)
Sau phản ứng :
$m_{dd} = 197a + 100 - a.44 = 153a + 100(gam)$
$n_{HCl\ dư} = 0,2 - 2a(mol)$
Suy ra :
$C\%_{HCl} = \dfrac{(0,2-2a).36,5}{153a + 100}.100\% = 2,28\%$
$\Rightarrow a = 0,066$
$C\%_{BaCl_2} = \dfrac{0,066.208}{0,066.153 + 100}.100\% = 12,47\%$