CaCO₃ + 2HCl -> CaCl₂ + CO₂ + H₂O (1)

MgCO₃ + 2HCl -> MgCl₂ + CO₂ + H₂O (2)

n_CO2=0,15(mol)

Đặt n_CaCO3=a

n_MgCO3=b

Ta có hệ:

\(\left\{{}\begin{matrix}100a+84b=13,4\\a+b=0,15\end{matrix}\right.\)

=>a=0,05;b=0,1

m_CaCO3=100.0,05=5(g)

m_MgCO3=13,4-5=8,4(g)

b;

n_HCl=2n_CO2=0,3(mol)

V_{dd HCl}=\(\dfrac{0,3}{1}=0,3\left(lít\right)\)

a) $CO_2 + Ca(OH)_2 \to CaCO_3 + H_2O$

n CaCO3 = n CO2 = x(mol)

m giảm = m CaCO3 - m CO2 

=> 3,36 = 100x -44x

=> x = 0,06(mol)

Gọi n MgCO3 = a(mol) ; n CaCO3 = b(mol)

=> 84a + 100b = 5,68(1)

$MgCO_3 + 2HCl \to MgCl_2 + CO_2 + H_2O$
$CaCO_3 + 2HCl \to CaCl_2 + CO_2 + H_2O$
n CO2 = a + b = x = 0,06(2) 

Từ (1)(2) suy ra a = 0,02 ; b = 0,04

%m MgCO3 = 0,02.84/5,68   .100% = 29,58%
%m CaCO3 = 100% -29,58% = 70,42%

b)

n MgCl2 = a = 0,02(mol)

n CaCl2 = b = 0,04(mol)

n HCl pư = 2a + 2b = 0,12(mol)

=> n HCl dư = 0,5.1 - 0,12 = 0,38(mol)

Vậy : 

CM MgCl2 = 0,02/1 = 0,02M

CM CaCl2 = 0,04/1 = 0,04M

CM HCl = 0,38/1 = 0,38M

a)

Gọi $n_{CaCO_3} = a; n_{MgCO_3} = b$

$\Rightarrow 100a + 84b = 28,4(1)$
$CaCO_3 + 2HCl \to CaCl_2 + CO_2  + H_2O$
$MgCO_3 + 2HCl \to MgCl_2 + CO_2 + H_2O$
$n_{CO_2} = a + b = \dfrac{6,72}{22,4} = 0,3(2)$

Từ (1)(2) suy ra a = 0,2 ; b = 0,1

$\%m_{CaCO_3} = \dfrac{0,2.100}{28,4}.100\% = 70,42\%$
$\%m_{MgCO_3} = 100\% -70,42\% = 29,58\%$

b)

$n_{HCl\ pư} = 2n_{CO_2} = 0,6(mol)$
$n_{HCl\ dư} = 0,6.1\% = 0,006(mol)$

$n_{HCl\ đã\ dùng} = 0,6 + 0,006 = 0,606(mol)$
$m_{dd\ HCl} = \dfrac{0,606.36,5}{29,2\%} = 75,75(gam)$
$V_{dd\ HCl} = \dfrac{75,75}{1,25} = 60,6(ml)$

a) MgO + 2HCl ---> MgCl₂ + H₂O (1)

MgCO₃ + 2HCl ---> MgCl₂ + H₂O + CO₂ (2) 

b) \(n_{CO_2}=\dfrac{m}{M}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)

=> \(m_{MgCO_3}=n.M=0,1.84=8,4\left(g\right)\)

\(m_{MgO}=16-8,4=8\left(g\right)\)

c) \(n_{MgO}=\dfrac{m}{M}=\dfrac{8}{40}=0,2\left(mol\right)\)

=> \(n_{HCl\left(1\right)}=0,4\left(mol\right)\); n_HCl(2) = 0,2(mol)

=> n_HCl = 0.4 + 0,2 = 0,6 (mol) 

=> V_HCl = \(\dfrac{n}{C_M}=\dfrac{0,6}{1,5}=0,4\left(l\right)=400\left(ml\right)\)

\(Đặt:n_{CaCO_3}=x\left(mol\right);K_2CO_3=y\left(mol\right)\\ Tacó:\left\{{}\begin{matrix}100x+138y=37,6\\x+y=0,3\left(BTNT\left(C\right)\right)\end{matrix}\right.\\ \Rightarrow\left\{{}\begin{matrix}x=0,1\\y=0,2\end{matrix}\right.\\ \%m_{CaCO_3}=26,6\%;\%m_{K_2CO_3}=73,4\%\)

Gọi $n_{MgCO_3} = a(mol) ; n_{CaCO_3} = b(mol) \Rightarrow 84a + 100 b = 5,68(1)$
$MgCO_3 + 2HCl \to MgCl_2 + CO_2 + H_2O$
$CaCO_3 + 2HCl \to CaCl_2 + CO_2 + H_2O$
$n_{CO_2} = a + b = \dfrac{1,344}{22,4} = 0,06(mol)(2)$

Từ (1)(2) suy ra a = 0,02;  b = 0,04

$\%m_{MgCO_3} = \dfrac{0,02.84}{5,68}.100\% = 29,58\%$

$\%m_{CaCO_3} = 100\% - 29,58\% = 70,42\%$

\(n_{BaCO_3}=\dfrac{19.7}{197}=0.1\left(mol\right)\)

\(n_{Ba\left(OH\right)_2}=0.15\cdot1=0.15\left(mol\right)\)

\(n_{MgCO_3}=a\left(mol\right),n_{CaCO_3}=b\left(mol\right)\)

\(\Rightarrow m_A=84a+100b=18.4\left(g\right)\left(1\right)\)

\(MgCO_3+2HCl\rightarrow MgCl_2+CO_2+H_2O\)

\(CaCO_3+2HCl\rightarrow CaCl_2+CO_2+H_2O\)

\(n_{CO_2}=a+b\left(mol\right)\)

TH1 : Không tạo muối axit , Ba(OH)₂ dư 

\(\Rightarrow n_{CO_2}=n_{BaCO_3}=0.1\left(mol\right)\)

\(\Rightarrow a+b=0.1\left(2\right)\)

\(\left(1\right),\left(2\right):a=-0.525,b=0.625\left(L\right)\)

TH2 : Phản ứng tạo hai muối vừa đủ 

\(n_{CO_2}=0.1+\left(0.15-0.1\right)\cdot2=0.2\left(mol\right)\)

\(\Rightarrow a+b=0.1\left(3\right)\)

\(\left(1\right),\left(3\right):a=b=0.1\)

\(\%MgCO_3=\dfrac{8.4}{18.4}\cdot100\%=45.65\%\)

\(\%CaCO_3=54.35\%\)

giúp mình với .mình ko bik lm

a, PT: \(CaCO_3+2HCl\rightarrow CaCl_2+CO_2+H_2O\)

\(MgCO_3+2HCl\rightarrow MgCl_2+CO_2+H_2O\)

Ta có: 100n_CaCO3 + 84n_MgCO3 = 14,2 (1)

Theo PT: \(n_{CO_2}=n_{CaCO_3}+n_{MgCO_3}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\left(2\right)\)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{CaCO_3}=0,1\left(mol\right)\\n_{MgCO_3}=0,05\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{CaCO_3}=\dfrac{0,1.100}{14,2}.100\%\approx70,42\%\\\%m_{MgCO_3}\approx29,58\%\end{matrix}\right.\)

b, Theo PT: \(n_{HCl}=2n_{CO_2}=0,3\left(mol\right)\Rightarrow C_{M_{HCl}}=\dfrac{0,3}{0,6}=0,5\left(M\right)\)

PTHH :

\(CaCO_3+2HCl\rightarrow CaCl_2+H_2O+CO_2\)

x                 2x               x           x          x 

\(MgCO_3+2HCl\rightarrow MgCl_2+H_2O+CO_2\uparrow\)

y                 2y               y              y          y 

Có:

\(\left\{{}\begin{matrix}100x+84y=14,2\\x+y=\dfrac{3,36}{22,4}=0,15\end{matrix}\right.\)

\(\Rightarrow x=0,1;y=0,05\)

\(a,\%m_{CaCO_3}=0,1.100:14,2.100\%\approx72,423\%\)

\(\%m_{MgCO_3}=100\%-72,423\%\approx29,577\%\)

\(b,C_{M\left(HCl\right)}=\dfrac{0,2+0,1}{0,6}=0,5\left(M\right)\)

Gọi số mol của CaCO3 và MgCO3 lần lượt là x và y => mhỗn hợp = PT(1)

Phương trình hóa học:

CaCO3 to→→�� CaO + CO2

  x mol            →      x mol

MgCO3 to→→�� MgO + CO2

  y mol           →         y mol

=>nCO2=PT(2)