\(Zn+2HCl->ZnCl_2+H_2\\ Mg+2HCl->MgCl_2+H_2\\ n_{Zn}=a\\ n_{Mg}=b\\ 65a+24b=11,3g\\ n_{H_2}=a+b=\dfrac{6,72}{22,4}=0,3\\ a=0,1\\ m_{Zn}=65.0,1=6,5g\)

Khối lượng sắt:mFe=0,46298*60,5=28 g=>mZn=32,5g

=>nFe=0,5;nZn=0,5

ta có:nCl- =2nFe+2nZn=2 mol =>nHCl=2mol

=>nH2 =1mol.=>V H2=44,8 lit

m muối =m kim loại +m Cl- =60,5 +2*35,5=131,5

131,5 tích nha

$Zn + H_2SO_4 \to ZnSO_4 + H_2$

$n_{Zn} = n_{H_2} = \dfrac{1,12}{22,4} = 0,05(mol)$

$\%m_{Zn} = \dfrac{0,05.65}{5,25}.100\% = 61,9\%$

$\%m_{Cu} =1 00\% -61,9\% = 38,1\%$

Pthh:

\(Zn+H2SO4->ZnSO\text{4+H2}\)

\(nZn=nH2=\dfrac{1,12}{22,4}=0,05mol\)

\(=>mZn=0,05.65=3,25g\)\(=>\%mZn=\dfrac{3,25}{5,25}.100\%=62\%\)

\(=>\%mCu=100-62=38\%\)

\(Fe+2HCl\rightarrow FeCl_2+H_2\\ n_{H_2}=n_{Fe}=0,15\left(mol\right)\\ \Rightarrow m_{Fe}=0,15.56=8,4\left(g\right)\\ ChấtrắnkhôngtanlàCu\\ Cu+Cl_2\text{ }\rightarrow CuCl_2\\ n_{Cu}=n_{Cl_2}=0,2\left(mol\right)\\ \Rightarrow m_{Cu}=0,2.64=12,8\left(g\right)\\ \%m_{Fe}=\dfrac{8,4}{8,4+12,8}.100=39,62\%\\ \%m_{Cu}=100-39,62=60,38\%\)

\(n_{H_2}=\dfrac{4,48}{22,4}=0,2\left(mol\right)\)

PTHH: Zn + 2HCl ---> ZnCl₂ + H₂

           0,2<--0,4<------0,2<-----0,2

=> \(\left\{{}\begin{matrix}\%m_{Zn}=\dfrac{0,2.65}{21,1}.100\%=61,61\%\\\%m_{ZnO}=100\%-61,61\%=38,39\%\end{matrix}\right.\)

\(n_{ZnO}=\dfrac{21,1-0,2.65}{81}=0,1\left(mol\right)\)

PTHH: ZnO + 2HCl ---> ZnCl₂ + H₂O

            0,1---->0,2------>0,1

=> \(C\%_{HCl}=\dfrac{\left(0,2+0,4\right).36,5}{200}.100\%=10,95\%\)

\(m_{mu\text{ố}i}=m_{ZnCl_2}=\left(0,1+0,2\right).136=40,8\left(g\right)\)

 PTHH

Mg + 2HCl ----> MgCl2 + H2      (1)

MgO + 2HCl -----> MgCl2 + H2O (2)

a) Theo pt(1) n Mg = n H2 = \(\frac{1,12}{22,4}\) = 0,05 (mol)

==> m Mg = 0,005 . 24=1,2 (g)

%m Mg =  \(\frac{1,2}{3,2}\). 100%= 37,5%

%m MgO= 100% - 37,5%= 62,5%

b)m dd sau pư = 3,2 + 246,9 - 0,05 . 2=250 (g)

Theo pt(1)(2)  n MgCl2(1) = n Mg = 0,05 mol

                         n MgCl2 (2) = n MgO=\(\frac{3,2-1,2}{40}\)=0,05(mol)

==> tổng n MgCl2 = 0,1 (mol)  ---->m MgCl2 = 9,5 (g)

C%(MgCl2)= \(\frac{9,5}{250}\) .100% = 3,8%

a, Ta có: 65n_Zn + 27n_Al = 11,9 (1)

PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)

\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

Theo PT: \(n_{H_2}=n_{Zn}+\dfrac{3}{2}n_{Al}=\dfrac{9,916}{24,79}=0,4\left(mol\right)\left(2\right)\)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{Zn}=0,1\left(mol\right)\\n_{Al}=0,2\left(mol\right)\end{matrix}\right.\)

⇒ m_Zn = 0,1.65 = 6,5 (g)

m_Al = 0,2.27 = 5,4 (g)

b, Theo PT: n_ZnCl2 = n_Zn = 0,1 (mol)

n_AlCl3 = n_Al = 0,2 (mol)

⇒ m _muối = 0,1.136 + 0,2.133,5 = 40,3 (g)

c, Theo PT: n_HCl = 2n_H2 = 0,8 (mol)

\(\Rightarrow m_{ddHCl}=\dfrac{0,8.36,5}{10\%}=292\left(g\right)\)

\(n_{H2}=\dfrac{1,12}{22,4}=0,05\left(mol\right)\)

Pt : \(Mg+2HCl\rightarrow MgCl_2+H_2|\)

        1          2               1         1

       0,05    0,1           0,05      0,05 

    \(MgO+2HCl\rightarrow MgCl_2+H_2O|\)

       1           2              1            1

      0,2       0,4            0,2

a) \(n_{Mg}=\dfrac{0,05.1}{1}=0,05\left(mol\right)\)

\(m_{Mg}=0,05.24=1,2\left(g\right)\)

\(m_{MgO}=9,2-1,2=8\left(g\right)\)

⁰/₀Mg = \(\dfrac{1,2.100}{9,2}=13,04\)⁰/₀

⁰/₀MgO = \(\dfrac{8.100}{9,2}=86,96\)⁰/₀

b) Có : \(m_{MgO}=8\left(g\right)\)

\(n_{MgO}=\dfrac{8}{40}=0,2\left(mol\right)\)

\(n_{HCl\left(tổng\right)}=0,1+0,4=0,5\left(mol\right)\)

\(m_{HCl}=0,5.36,5=18,25\left(g\right)\)

\(m_{ddHCl}=\dfrac{18,25.100}{14,6}=125\left(g\right)\)

c) \(n_{MgCl2\left(tổng\right)}=0,05+0,2=0,25\left(mol\right)\)

⇒ \(m_{MgCl2}=0,25.95=23,75\left(g\right)\)

\(m_{ddspu}=9,2+125-\left(0,05.2\right)=134,1\left(g\right)\)

\(C_{MgCl2}=\dfrac{23,75.100}{134,1}=17,71\)⁰/₀

 Chúc bạn học tốt

a)\(n_{H_2}=\dfrac{1,12}{22,4}=0,05\left(mol\right)\)

PTHH: Mg + 2HCl → MgCl₂ + H₂

Mol:    0,05    0,1           0,05        0,05

PTHH: MgO + 2HCl → MgCl₂ + H₂O

Mol:     0,2         0,4         0,2

\(\%m_{Mg}=\dfrac{0,05.24.100\%}{9,2}=13,04\%;\%m_{MgO}=100-13,04=86,96\%\)

\(n_{MgO}=\dfrac{9,2-0,05.24}{40}=0,2\left(mol\right)\)

b,\(m_{HCl}=\left(0,1+0,4\right).36,5=18,25\left(g\right)\)

\(m_{ddHCl}=\dfrac{18,25.100}{14,6}=125\left(g\right)\)

c,m_{dd sau pứ} = 9,2+125-0,05.2 = 134,1 (g)

 \(C\%_{ddMgCl_2}=\dfrac{\left(0,05+0,2\right).95.100\%}{134,1}=17,71\%\)

\(Mg + 2HCl \rightarrow MgCl_2 + H_2\)     (1)

\(MgO + 2HCl \rightarrow MgCl_2 + H_2O\)      (2)

Khí thu được là H₂

\(n_{H_2}= \dfrac{1,12}{22,4}=0,05 mol\)

Theo PTHH (1):

\(n_{Mg}= n_{H_2}= 0,05 mol\)

\(\Rightarrow m_{Mg}= 0,05 . 24= 1,2 g\)

\(\Rightarrow m_{MgO}= 9,2 - 1,2= 8g\)

C%_\(Mg\)= \(\dfrac{1,2}{9,2} .100\)%=13,04%

C%_\(MgO\)= 100% - 13,04%=86,96%

b)

\(n_{MgO}= \dfrac{8}{40}=0,2 mol\)

Theo PTHH (1) và (2):

\(n_{HCl(1)}= 2n_{Mg}= 0,1 mol\)

\(n_{HCl(2)}= 2n_{MgO}= 0,4 mol\)

Suy ra: \(n_{HCl}= n_{HCl(1)} + n_{HCl(2)}\)

                     \(= 0,1 + 0,4= 0,5 mol\)

\(\Rightarrow m_{HCl}= 0,5 . 36,5= 18,25g\)

\(\Rightarrow m_{dd HCl} = \dfrac{18,25 . 100%}{14,6%}=125 g\)

_c)

\(\)Dung dịch sau pư: MgCl₂

Theo PTHH:

\(n_{MgCl_2}= \dfrac{1}{2} n_{HCl}= 0,25 mol\)

\(\Rightarrow m_{MgCl_2}= 0,25 . 95=23,75g\)

\(m_{dd sau pư} = m_{Mg} + m_{MgO} + m_{dd HCl}- m_{H_2}\)

               \(= 9,2 + 125 + 2 . 0,05\)

             \(=134,1 g\)

C%_{\(MgCl_2\)}=\(\dfrac{23,75}{134,1}. 100\)%=17,71%