==0,06 (mol)

 ko pứ

0,06    0,12                ←0,06          (mol)

%=.100 % ≈25,85 %

%=100 % - 25,85 %=74,15 %

///

=0,12.26,5=4,38 (g)

= =29,2 (g)

\(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)

PTHH: Fe + 2HCl --> FeCl₂ + H₂

         0,15<--------------------0,15

=> \(\%Fe=\dfrac{0,15.56}{14,8}.100\%=56,757\%\)

=> \(\%Cu=100\%-56,757\%=43,243\%\)

nH2 = 3,36/22,4 = 0,15 (mol)

PTHH: Fe + 2HCl -> FeCl2 + H2

nFe = 0,15 (mol)

mFe = 0,15 . 56 = 8,4 (g)

%mFe = 8,4/14,8 = 56,75%

%mCu = 100% - 56,75% = 43,25%

1)

Fe + 2HCl --> FeCl₂ + H₂

Cu + 2H₂SO₄ --> CuSO₄ + SO₂ + 2H₂O

2)

- Xét TN1:

\(n_{H_2}=\dfrac{3,36}{22,4}=0,15\left(mol\right)\)

PTHH: Fe + 2HCl --> FeCl₂ + H₂

         0,15<------------------0,15

=> m_Fe = 0,15.56 = 8,4 (g)

\(\left\{{}\begin{matrix}\%m_{Fe}=\dfrac{8,4}{14,8}.100\%=56,757\%\\\%m_{Cu}=100\%-56,757\%=43,243\%\end{matrix}\right.\)

3) 

- Xét TN2:

\(n_{Cu}=\dfrac{29,6.43,243\%}{64}=0,2\left(mol\right)\)

PTHH: Cu + 2H₂SO₄ --> CuSO₄ + SO₂ + 2H₂O

            0,2-------------------------->0,2

=> V = 0,2.22,4 = 4,48 (l)

\(n_{HCl}=0,3.2=0,6\left(mol\right)\\ n_{H_2}=\dfrac{5,6}{22,4}=0,25\left(mol\right)\\ 2Al+6HCl\rightarrow2AlCl_3+3H_2\\ Fe+2HCl\rightarrow FeCl_2+H_2\\ Vì:\dfrac{0,6}{2}>\dfrac{0,25}{1}\Rightarrow HCldư\\ Đặt:n_{Al}=t\left(mol\right);n_{Fe}=r\left(mol\right)\\ \left(t,r>0\right)\\ \Rightarrow\left\{{}\begin{matrix}27t+56r=8,3\\1,5t+r=0,25\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}t=0,1\\r=0,1\end{matrix}\right.\\ \Rightarrow m_{Al}=0,1.27=2,7\left(g\right);m_{Fe}=0,1.56=5,6\left(g\right)\\ b,n_{AlCl_3}=n_{Al}=0,1\left(mol\right)\Rightarrow m_{AlCl_3}=0,1.133,5=13,35\left(g\right)\\ n_{Fe}=n_{FeCl_2}=0,1\left(mol\right)\Rightarrow m_{ddFeCl_2}=127.0,1=12,7\left(g\right)\\ m_{ddHCl}=300.1,15=345\left(g\right)\\ m_{ddsau}=8,3+345-0,25.2=352,8\left(g\right)\)

\(n_{HCl\left(dư\right)}=0,6-0,25.2=0,1\left(mol\right)\\ \Rightarrow m_{ddHCl}=0,1.36,5=3,65\left(g\right)\\ C\%_{ddHCl\left(dư\right)}=\dfrac{3,65}{352,8}.100\approx1,035\%\\ C\%_{ddAlCl_3}=\dfrac{13,35}{352,8}.100\approx3,784\%\\ C\%_{ddFeCl_2}=\dfrac{12,7}{352,8}.100\approx3,6\%\)

Ta có: \(n_{H_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)

PT: \(Fe+2HCl\rightarrow FeCl_2+H_2\)

Theo PT: \(n_{HCl}=2n_{H_2}=0,2\left(mol\right)\Rightarrow C_{M_{HCl}}=\dfrac{0,2}{0,1}=2\left(M\right)\)

\(n_{Fe}=n_{H_2}=0,1\left(mol\right)\Rightarrow m_{Fe}=0,1.56=5,6\left(g\right)\)

\(\Rightarrow m_{Cu}=20-5,6=14,4\left(g\right)\)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{Fe}=\dfrac{5,6}{20}.100\%=28\%\\\%m_{Cu}=72\%\end{matrix}\right.\)

\(n_{H_2}=\dfrac{1,12}{22,4}=0,05(mol)\\ Fe+2HCl\to FeCl_2+H_2\\ \Rightarrow n_{Fe}=0,05(mol)\\ \Rightarrow \%_{Fe}=\dfrac{0,05.56}{20}.100\%=14\%\\ \Rightarrow \%_{Cu}=100\%-14\%=86\%\)

Fe+2HCl->FeCl2+H2

0,05--------------------0,05

n H2=1,12\22,4=0,05 mol

=>m Fe=0,05.56=2,8g

=>%m Fe=2,8\20.100=14%

=>%m Cu=100-14=86%

Ta chỉ có 1 PTHH xảy ra: 

\(1\)) \(Fe+2HCl\rightarrow FeCl2+H2\)

Có \(nH2=\dfrac{1,12}{22,4}=0,05mol\)

Dựa vào PTHH ) \(nH2=nFe=0,05mol\)

Vậy: \(mFe=0,05.56=2,8g\)

\(\rightarrow\%Fe=\dfrac{2,8}{20}.100=14\%\)

Vậy \(\%Cu=100\%-14\%=86\%\)

Ta có: \(\left\{{}\begin{matrix}x=Fe\\y=Cu\end{matrix}\right.\) trong 40g hh

\(n_{H_2}=\dfrac{V_{H_2}}{22,4}=\dfrac{11,2}{22,4}=0,5mol\)

PTHH: Fe + 2HCl \(\rightarrow\) FeCl₂ + H₂

  TL:      1        2            1         1

mol:     0,5     \(\leftarrow\)  1    \(\leftarrow\)   0,5  \(\leftarrow\) 0,5

\(m_{Fe}=n.M=0,5.56=28g\)

\(\%m_{Fe}=\dfrac{m_{Fe}}{m_{hh}}.100\%=\dfrac{28}{40}.100\%=70\%\)

\(\%m_{Cu}=100\%-70\%=30\%\)

a) n Fe = a(mol) ; n Cu = b(mol)

=> 56a + 64b = 4,8(1)

n SO2 = 2,24/22,4 = 0,1(mol)

Bảo toàn e :

3n Fe + 2n Cu = 2n SO2

<=> 3a + 2b = 0,2(2)

Từ (1)(2) suy ra a = b = 0,04

%m Fe = 0,04.56/4,8  .100% = 46,67%

%m Cu = 100% -46,67% = 53,33%

b)

n KOH = 0,15

Ta có :

1 < n KOH / n SO2 = 0,15/0,1 = 1,5 < 2 nên muối sinh ra là Na2SO3(x mol) và NaHSO3(y mol)

2NaOH + SO2 $\to$ Na2SO3 + H2O

NaOH + SO2 $\to$ NaHSO3

Theo PTHH :

n SO2 = a + b = 0,1

n NaOH = 2a + b = 0,15

Suy ra a= 0,05 ; b = 0,05

m muối = 0,05.126 + 0,05.104 = 11,5 gam

Bài 2 :

- Gọi số mol Fe và Cu lần lượt là a, b mol

Ta có : mhh = mFe + mCu = 56a + 64b = 4,8

Bte : 3a + 2b = 0,2 

=> a = b =0,04mol

a, Ta có : mFe =n.M = 2,24g ( 46,7% )

=> %Cu = 53,3%

b, Ta thấy sau phản ứng thu được K+, SO3-2 xmol, HSO3- y mol

BtS : x + y = 0,1 

BTĐT : 2x + y = 0,15 

=> x =y = 0,05 mol

=> mM = mK2SO3 + mKHSO3 = 13,9g