Mình làm vậy nè, mình không chắc đâu nha ><

Gọi a, b lần lượt là số mol của Al và Fe

2Al + 6HCl \(\rightarrow\) 2AlCl₃ + 3H₂\(\uparrow\)

a----------3a----------a---------1,5a (mol)

Fe + 2HCl \(\rightarrow\) FeCl₂ + H₂\(\uparrow\)

b---------2b--------b-------b (mol)

Sau khi phản ứng kết thúc trung hoà dung dịch đó bằng NaOH \(\rightarrow\) HCl dư

HCl + NaOH \(\rightarrow\) NaCl + H₂O

n_HCl = n_NaOH = V_dd . C_M = 0.3 (mol)

n_{HCl ban đầu} = 2 . 1,25 = 2,5 (mol)

\(\rightarrow\) n_{HCl phản ứng} = 2,5 - 0.3 = 2.2 (mol)

Ta có: \(\left\{{}\begin{matrix}27a+56b=38,8\\3a+2b=2,2\end{matrix}\right.\)

\(\Rightarrow\) \(\left\{{}\begin{matrix}a=0,4\\b=0,5\end{matrix}\right.\)

m_Al = n . M = 0,4 . 27 = 10,8 (g)

m_Fe = 0,5 . 56 = 28 (g)

a) %m_Al = \(\dfrac{m_{Al}}{m_{hh}}.100\) = \(\dfrac{10,8}{38,8}.100\) \(\approx\) 27,84%

%m_Fe = 100% - 27,84% \(\approx\) 72,16%

b) V_H2 = (1,5a + b) . 22,4 = (1,5 . 0,4 + 0,5) . 22,4 = 24,64 (l)

gọi n_Mg=x và n_Al = y

n_HCl= 0,5 x 2= 1 mol

x 2x x

y 3y y

do dd sau pư trung hòa được với NaOH thu được dd x

→ HCl dư và chỉ có HCl tác dụng với NaOH

→ n_{HCl dư}= 1 - 2x -3y mol

ta có hệ pt : \(\left\{{}\begin{matrix}24x+27y=7,5\\1-2x-3y=0,3\end{matrix}\right.\rightarrow\left\{{}\begin{matrix}x=0,2\\y=0,1\end{matrix}\right.\)

→m_Mg = 0,2 x 24 = 4,8 g ; m_Al= 0,1 x 27 = 2,7 g

Vddx = 0,5 + 0,3 = 0,8 lít

C_{M MgCl2}=\(\dfrac{0,2}{0,8}\)=0,25 M

C_{M AlCl3} =\(\dfrac{0,1}{0,8}\)= 0,125 M

C_{M NaCl} =\(\dfrac{0,3}{0,8}\)= 0,375 M

a, \(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

\(Zn+2HCl\rightarrow ZnCl_2+H_2\)

\(m_{HCl}=730.10\%=73\left(g\right)\Rightarrow n_{HCl}=\dfrac{73}{36,5}=2\left(mol\right)\)

\(n_{H_2}=\dfrac{17,92}{22,4}=0,8\left(mol\right)\)

→ n_HCl > 2n_H2 ⇒ HCl dư.

Ta có: 27n_Al + 65n_Zn = 23,8 (1)

Theo PT: \(n_{H_2}=\dfrac{3}{2}n_{Al}+n_{Zn}=0,8\left(mol\right)\left(2\right)\)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{Al}=0,4\left(mol\right)\\n_{Zn}=0,2\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}\%m_{Al}=\dfrac{0,4.27}{23,8}.100\%\approx45,4\%\\\%m_{Zn}\approx54,6\%\end{matrix}\right.\)

b, Theo PT: \(\left\{{}\begin{matrix}n_{AlCl_3}=n_{Al}=0,4\left(mol\right)\\n_{ZnCl_2}=n_{Zn}=0,2\left(mol\right)\\n_{HCl\left(pư\right)}=2n_{H_2}=1,6\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow n_{HCl\left(dư\right)}=2-1,6=0,4\left(mol\right)\)

Ta có: m _{dd sau pư} = 23,8 + 730 - 0,8.2 = 752,2 (g)

\(\Rightarrow\left\{{}\begin{matrix}C\%_{AlCl_3}=\dfrac{0,4.133,5}{752,2}.100\%\approx7,1\%\\C\%_{ZnCl_2}=\dfrac{0,2.136}{752,2}.100\%\approx3,62\%\\C\%_{HCl}=\dfrac{0,4.36,5}{752,2}.100\%\approx1,94\%\end{matrix}\right.\)

a)

Gọi $n_{Zn} = a(mol) ; n_{Al} = b(mol) \Rightarrow 65a + 27b = 11,9(1)$

$Zn + 2HCl \to ZnCl_2 + H_2$
$2Al + 6HCl \to 2AlCl_3 + 3H_2$
Theo PTHH : 

$n_{H_2} = a + 1,5b = \dfrac{8,96}{22,4} = 0,4(2)$

Từ (1)(2) suy ra : a = 0,1; b = 0,2

$m_{Zn} = 0,1.65 = 6,5(gam)$

$m_{Al} = 0,2.27 = 5,4(gam)$

b) $n_{HCl} = 2n_{H_2} = 0,8(mol)$
$C\%_{HCl} = \dfrac{0,8.36,5}{125}.100\% = 23,36\%$

$a)PTHH:2Al+6HCl\to 2AlCl_3+3H_2$

$n_{H_2}=\dfrac{5,04}{22,4}=0,225(mol)$

$\Rightarrow n_{Al}=0,15(mol)$

$\Rightarrow \%m_{Al}=\dfrac{0,15.27}{9,45}.100\%\approx 42,86\%$

$\Rightarrow \%m_{Cu}=100-42,86=57,14\%$

$b)$ Theo PT: $n_{HCl}=2n_{H_2}=0,45(mol)$

$\Rightarrow C_{M_{HCl}}=\dfrac{0,45.110\%}{0,5}=0,99M$

a) \(Zn+2HCl\rightarrow ZnCl_2+H_2\)

\(Fe+2HCl\rightarrow FeCl_2+H_2\)

\(Đặt:n_{Zn}=x\left(mol\right);n_{Fe}=y\left(mol\right)\)

\(n_{H_2}=0,4\left(mol\right)\)

Theo đề ta có hệ \(\left\{{}\begin{matrix}65x+56y=24,2\\x+y=0,4\end{matrix}\right.\)

=> x=0,2 ; y=0,2

\(\%m_{Zn}=\dfrac{0,2.65}{24,2}.100=53,72\%;\%m_{Fe}=46,28\%\)

b)Bảo toàn nguyên tố H: \(n_{HCl}=2n_{H_2}=0,8\left(mol\right)\)

=> \(V_{HCl}=\dfrac{0,8}{2,5}=0,32\left(l\right)\)

c) \(n_{FeCl_2}=0,2\left(mol\right);n_{ZnCl_2}=0,2\left(mol\right)\)

=> \(CM_{FeCl_2}=\dfrac{0,2}{0,32}=0,625\left(mol\right)\)

\(CM_{ZnCl_2}=\dfrac{0,2}{0,32}=0,625\left(mol\right)\)

a, PT: \(Zn+2HCl\rightarrow ZnCl_2+H_2\)

\(2Al+6HCl\rightarrow2AlCl_3+3H_2\)

Gọi: \(\left\{{}\begin{matrix}n_{Zn}=x\left(mol\right)\\n_{Al}=y\left(mol\right)\end{matrix}\right.\) ⇒ 65x + 27y = 17,05 (1)

Ta có: \(n_{H_2}=\dfrac{9,52}{22,4}=0,425\left(mol\right)\)

Theo PT: \(n_{H_2}=n_{Zn}+\dfrac{3}{2}n_{Al}=x+\dfrac{3}{2}y=0,425\left(2\right)\)

Từ (1) và (2) \(\Rightarrow\left\{{}\begin{matrix}n_{Zn}=0,2\left(mol\right)\\n_{Al}=0,15\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}m_{Zn}=0,2.65=13\left(g\right)\\m_{Al}=0,15.27=4,05\left(g\right)\end{matrix}\right.\)

b, Theo PT: \(\left\{{}\begin{matrix}n_{ZnCl_2}=n_{Zn}=0,2\left(mol\right)\\n_{AlCl_3}=n_{Al}=0,15\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}C_{M_{ZnCl_2}}=\dfrac{0,2}{0,5}=0,4\left(M\right)\\C_{M_{AlCl_3}}=\dfrac{0,15}{0,5}=0,3\left(M\right)\end{matrix}\right.\)

c, Ta có: m _{dd HCl} = 1,05.500 = 525 (g)

m _{dd sau pư} = m_hh + m _{dd HCl} - m_H2 = 541,2 (g)

\(\Rightarrow\left\{{}\begin{matrix}C\%_{ZnCl_2}=\dfrac{0,2.136}{541,2}.100\%\approx5,03\%\\C\%_{AlCl_3}=\dfrac{0,15.133,5}{541,2}.100\%\approx3,7\%\end{matrix}\right.\)