\(n_{CuSO_4}=\dfrac{200.16\%}{160}=0,2\left(mol\right)\)

PTHH :

\(CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2\downarrow+Na_2SO_4\)

0,2              0,4                  0,2               0,2 

\(m_{NaOH}=0,4.40=16\left(g\right)\)

\(m_{ddNaOH}=\dfrac{16.100}{10}=160\left(g\right)\)

\(c,m_{Na_2SO_4}=0,2.142=28,4\left(g\right)\)

\(m_{ddNa_2SO_4}=200+160-\left(0,2.98\right)=340,4\left(g\right)\)

\(C\%_{Na_2SO_4}=\dfrac{28,4}{240,4}.100\%\approx8,34\%\)

\(d,PTHH:\)

\(Cu\left(OH\right)_2\underrightarrow{t^o}CuO+H_2O\)

0,2               0,2 

\(m_{CuO}=0,2.80=16\left(g\right)\)

a, \(CuSO_4+2NaOH\rightarrow Cu\left(OH\right)_2+Na_2SO_4\)

b, \(m_{CuSO_4}=200.16\%=32\left(g\right)\Rightarrow n_{CuSO_4}=\dfrac{32}{160}=0,2\left(mol\right)\)

\(n_{NaOH}=2n_{CuSO_4}=0,4\left(mol\right)\Rightarrow m_{ddNaOH}=\dfrac{0,4.40}{10\%}=160\left(g\right)\)

c, \(n_{Cu\left(OH\right)_2}=n_{Na_2SO_4}=n_{CuSO_4}=0,2\left(mol\right)\)

\(\Rightarrow C\%_{Na_2SO_4}=\dfrac{0,2.142}{200+160-0,2.98}.100\%\approx8,34\%\)

d, \(Cu\left(OH\right)_2\underrightarrow{t^o}CuO+H_2O\)

\(n_{CuO}=n_{Cu\left(OH\right)_2}=0,2\left(mol\right)\Rightarrow m_{CuO}=0,2.80=16\left(g\right)\)

PTHH: \(CuCl_2+2NaOH\rightarrow2NaCl+Cu\left(OH\right)_2\downarrow\)

            \(Cu\left(OH\right)_2\xrightarrow[]{t^o}CuO+H_2O\)

Ta có: \(\left\{{}\begin{matrix}n_{CuCl_2}=0,2\cdot2=0,4\left(mol\right)\\n_{NaOH}=0,2\cdot2=0,4\left(mol\right)\end{matrix}\right.\)

Xét tỉ lệ: \(\dfrac{0,4}{1}>\dfrac{0,4}{2}\) \(\Rightarrow\) CuCl₂ còn dư

\(\Rightarrow\left\{{}\begin{matrix}n_{NaCl}=0,4\left(mol\right)\\n_{Cu\left(OH\right)_2}=0,2\left(mol\right)=n_{CuO}=n_{CuCl_2\left(dư\right)}\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}m_{CuO}=0,2\cdot80=16\left(g\right)\\C_{M_{NaCl}}=\dfrac{0,4}{0,2+0,2}=1\left(M\right)\\C_{M_{CuCl_2}}=\dfrac{0,2}{0,4}=0,5\left(M\right)\\\end{matrix}\right.\)

\(a,2NaOH+MgSO_4\rightarrow Mg\left(OH\right)_2+Na_2SO_4\\ n_{NaOH}=0,5.1=0,5\left(mol\right)\\ b,n_{Mg\left(OH\right)_2}=\dfrac{0,5}{2}=0,25\left(mol\right)=n_{Na_2SO_4}\\ m_{kt}=m_{Mg\left(OH\right)_2}=58.0,25=14,5\left(g\right)\\ c,V_{ddX}=V_{ddNaOH}+V_{ddMgSO_4}=0,5+0,5=1\left(l\right)\\ C_{MddNa_2SO_4}=\dfrac{0,25}{1}=0,25\left(M\right)\)

a. PTHH: 3NaOH + AlCl₃ ---> Al(OH)₃↓ + 3NaCl (1)

Ta có: \(C_{\%_{NaOH}}=\dfrac{m_{NaOH}}{100}.100\%=12\%\)

=> m_NaOH = 12(g)

=> \(n_{NaOH}=\dfrac{12}{40}=0,3\left(mol\right)\)

Ta lại có: \(C_{\%_{AlCl_3}}=\dfrac{m_{AlCl_3}}{200}.100\%=13,35\%\)

=> \(m_{AlCl_3}=26,7\left(g\right)\)

=> \(n_{AlCl_3}=\dfrac{26,7}{133,5}=0,2\left(mol\right)\)

Ta thấy: \(\dfrac{0,3}{3}< \dfrac{0,2}{1}\)

Vậy AlCl₃ dư

Theo PT₍₁₎: \(n_{Al\left(OH\right)_3}=\dfrac{1}{3}.n_{NaOH}=\dfrac{1}{3}.0,3=0,1\left(mol\right)\)

=> \(m_{Al\left(OH\right)_3}=0,1.78=7,8\left(g\right)\)

b. Ta có: \(m_{dd_{NaCl}}=12+200-7,8=204,2\left(g\right)\)

Theo PT₍₁₎: \(n_{NaCl}=n_{NaOH}=0,3\left(mol\right)\)

=> \(m_{NaCl}=0,3.58,5=17,55\left(g\right)\)

=> \(C_{\%_{NaCl}}=\dfrac{17,55}{204,2}.100\%=8,59\%\)

c. PTHH: 2Al(OH)₃ ---t^o---> Al₂O₃ + 3H₂O (2)

Theo PT₍₂₎: \(n_{Al_2O_3}=\dfrac{1}{2}.n_{Al\left(OH\right)_3}=\dfrac{1}{2}.0,1=0,05\left(mol\right)\)

=> \(m_{Al_2O_3}=0,05.102=5,1\left(g\right)\)

\(n_{CuCl_2}=2.0,2=0,4(mol)\\ n_{NaOH}=2.0,2=0,4(mol)\\ a,CuCl_2+2NaOH\to Cu(OH)_2+2NaCl\\ Cu(OH)_2\xrightarrow{t^o}CuO+H_2O\\ b,\dfrac{n_{CuCl_2}}{1}>\dfrac{n_{NaOH}}{2}\Rightarrow CuCl_2\text{ dư}\\ \Rightarrow n_{CuO}=0,2(mol)\\ \Rightarrow m_{CuO}=0,2.80=16(g)\\ c,n_{CuCl_2(dư)}=0,4-0,2=0,2(mol)\\n_{NaCl}=0,2(mol)\\ \Rightarrow m_{CuCl_2(dư)}=0,2.135=27(g)\\ m_{NaCl}=0,2.58,5=11,7(g)\)

a, \(CuCl_2+2NaOH\rightarrow2NaCl+Cu\left(OH\right)_2\)

\(Cu\left(OH\right)_2\underrightarrow{t^o}CuO+H_2O\)

b, \(n_{CuCl_2}=\dfrac{27}{135}=0,2\left(mol\right)\)

Theo PT: \(n_{CuO}=n_{Cu\left(OH\right)_2}=n_{CuCl_2}=0,2\left(mol\right)\)

\(\Rightarrow m_{CuO}=0,2.80=16\left(g\right)\)

c, \(n_{NaOH}=2n_{CuCl_2}=0,4\left(mol\right)\)

\(\Rightarrow C\%_{NaOH}=\dfrac{0,4.40}{200}.100\%=8\%\)

\(n_{CuSO_4}=2.0,34=0,68(mol)\\ a,CuSO_4+2NaOH\to Na_2SO_4+Cu(OH)_2\downarrow\\ Cu(OH)_2\xrightarrow{t^o}CuO+H_2O\\ \Rightarrow n_{Cu(OH)_2}=0,68(mol)\\ \Rightarrow m_{Cu(OH)_2}=0,68.98=66,64(g)\\ b,n_{CuO}=0,68(mol)\\ \Rightarrow m_{CuO}=0,68.80=54,4(g)\\ c,V_{dd_{NaOH}}=\dfrac{200}{1,25}=160(ml)\\ n_{NaOH}=\dfrac{200.32\%}{100\%.40}=1,6(mol)\)

Vì \(\dfrac{n_{CuSO_4}}{1}<\dfrac{n_{NaOH}}{2}\) nên \(NaOH\) dư

\(\Rightarrow n_{NaOH(dư)}=1,6-0,68.2=0,24(mol); n_{Na_2SO_4}=0,68(mol)\\ \Rightarrow \begin{cases} C_{M_{NaOH(dư)}}=\dfrac{0,24}{0,16}=1,5M\\ C_{M_{Na_2SO_4}}=\dfrac{0,68}{0,16}=4,25M \end{cases}\)