a) Đặt: nMg=x(mol); nZnO=y(mol)

nH2SO4= 0,2(mol)

PTHH: Mg + H2SO4 -> MgSO4 + H2

x___________x____x_______x(mol)

ZnO + H2SO4 -> ZnSO4 + H2O

y____y______y(mol)

Ta có: 

\(\left\{{}\begin{matrix}24x+81y=12,9\\22,4x=4,48\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}x=0,2\\y=0,1\end{matrix}\right.\)

mMg=0,2.24=4,8(g)

%mMg=(4,8/12,9).100=37,209%

=>%mZnO=62,791%

b) nH2SO4=x+y=0,3(mol)

=> \(C\%ddH2SO4=\dfrac{0,3.98}{120}.100=24,5\%\)

$n_{H_2} = \dfrac{6,72}{22,4} = 0,3(mol)$
$n_{Fe_2O_3} = \dfrac{40}{160} = 0,25(mol)$
$Fe_2O_3 + 3H_2 \xrightarrow{t^o} 2Fe + 3H_2O$

$n_{Fe_2O_3} : 1 = 0,25 > n_{H_2} : 3 = 0,1$ nên $Fe_2O_3$ dư

$n_{Fe} = \dfrac{2}{3}n_{H_2} = 0,2(mol)$
$n_{Fe_2O_3\ pư} = \dfrac{1}{3}n_{H_2} = 0,1(mol)$

$n_{Fe_2O_3\ dư} = 0,25 - 0,1 = 0,15(mol)$

Suy ra : 

$\%m_{Fe} = \dfrac{0,1.56}{0,1.56 + 0,15.160}.100\% = 18,92\%$

Gọi x,y lần lượt là số mol của Al, Fe

n_H2 = \(\dfrac{8,96}{22,4}\)=0,4 mol

Pt: 2Al + 3H₂SO₄ --> Al₂(SO₄)₃ + 3H₂

......x.................................0,5x...........1,5x

.....Fe + H₂SO₄ --> FeSO₄ + H₂

.......y..........................y............y

Ta có hệ pt:

 {27x+56y=11

   1,5x+y=0,4

⇔x=0,2, y=0,1

% m_Al = \(\dfrac{0,2.27}{11}\).100%=49,1%

% m_Fe = \(\dfrac{0,1.56}{11}\).100%=50,9%

m_Al2(SO4)3 = 0,5x . 342 = 0,5 . 0,2 . 342 = 34,2 (g)

m_FeSO4 = 152y = 152 . 0,1 = 15,2 (g)

Gọi CTTQ: M_xO_y

Pt: M_xO_y + yH₂ --to--> xM + yH₂O

\(\dfrac{0,4}{y}\)<-------0,4

Ta có: 232,2=\(\dfrac{0,4}{y}\)(56x+16y)

⇔23,2=\(\dfrac{22,4x}{y}\)+6,4

⇔\(\dfrac{22,4x}{y}\)=16,8

⇔22,4x=16,8y

⇔x:y=3:4

Vậy CTHH của oxit: Fe₃O₄

\(a)n_{H_2SO_4}=0,15.2=0,3mol\\ FeO+H_2SO_4\rightarrow FeSO_4+H_2O\\ n_{FeO}=n_{FeSO_4}=n_{H_2SO_4}=0,3mol\\ \%m_{FeO}=\dfrac{0,3.72}{22,4}\cdot100\%=96,43\%\\ \%m_{CuO}=100\%-96,43\%=3,57\%\\ b)C_{M_{FeSO_4}}=\dfrac{0,3}{0,15}=2M\)

Các bạn giúp mình ạ! 

Anh hnamyuh anh giúp em nốt phần bài 1 ạ! 

\(a,n_{H_2}=\dfrac{4,48}{22,4}=0,2mol\\ Fe+2HCl\rightarrow FeCl_2+H_2\\ n_{Fe}=n_{H_2}=0,2mol\\ m_{Fe}=0,2.56=11,2g\\ m_{Cu}=25-11,2=13,8g\\ b,\%m_{Fe}=\dfrac{11,2}{25}\cdot100=44,8\%\\ \%m_{Cu}=100-44,8=55,2\%\)
c, Gọi CTHH của sắt là \(Fe_xO_y\)

\(Fe_xO_y+yH_2\xrightarrow[t^0]{}xFe+yH_2O\\ \Rightarrow n_{Fe_xO_y}=n_{H_2}:y\\ \Leftrightarrow\dfrac{11,6}{56x+16y}=\dfrac{0,2}{y}\\ \Leftrightarrow11,6y=11,2x+3,2y\\ \Leftrightarrow11,6y-3,2y=11,2x\\ \Leftrightarrow8,4y=11,2x\\ \Leftrightarrow\dfrac{x}{y}=\dfrac{8,4}{11,2}=\dfrac{3}{4}\\ \Rightarrow x=3;y=4\\ \Rightarrow CTHH:Fe_3O_4\)

PTHH: \(Zn+2HCl\rightarrow ZnCl_2+H_2\uparrow\)

Ta có: \(n_{H_2}=\dfrac{6,72}{22,4}=0,3\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}n_{Zn}=0,3\left(mol\right)=n_{ZnCl_2}\\n_{HCl}=0,6\left(mol\right)\end{matrix}\right.\) \(\Rightarrow\left\{{}\begin{matrix}\%m_{Zn}=\dfrac{0.3\cdot65}{35,5}\cdot100\%\approx54,93\%\\\%m_{Cu}=45,07\%\\C\%_{HCl}=\dfrac{0,6\cdot36,5}{500}\cdot100\%=4,38\%\\m_{ZnCl_2}=0,3\cdot136=40,8\left(g\right)\end{matrix}\right.\)

Mặt khác: \(\left\{{}\begin{matrix}m_{Cu}=35,5-0,3\cdot65=16\left(g\right)\\m_{H_2}=0,3\cdot2=0,6\left(g\right)\end{matrix}\right.\)

\(\Rightarrow m_{dd}=m_{KL}+m_{ddHCl}-m_{Cu}-m_{H_2}=518,9\left(g\right)\)

\(\Rightarrow C\%_{ZnCl_2}=\dfrac{40,8}{518,9}\cdot100\%\approx7,86\%\)