a, \(4Al+3O_2\underrightarrow{t^o}2Al_2O_3\)

b, \(n_{Al_2O_3}=\dfrac{20,4}{102}=0,2\left(mol\right)\)

Theo PT: \(n_{O_2}=\dfrac{3}{2}n_{Al_2O_3}=0,3\left(mol\right)\Rightarrow V_{O_2}=0,3.22,4=6,72\left(l\right)\)

c, \(V_{kk}=\dfrac{V_{O_2}}{20\%}=33,6\left(l\right)\)

Đặt \(\left\{{}\begin{matrix}n_{Mg}=x\left(mol\right)\\n_{Fe}=y\left(mol\right)\end{matrix}\right.\)

Theo đề: \(m_{hh}=36\left(g\right)\)

\(\Rightarrow m_{Mg}+m_{Fe}=36\\ \Rightarrow24x+56y=36\left(1\right)\)

\(PTHH:2Mg+O_2\underrightarrow{t^o}2MgO\\ \left(mol\right)....x\rightarrow...0,5x.....x\\ PTHH:3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\\ \left(mol\right)....y\rightarrow...\dfrac{2}{3}y....\dfrac{1}{3}y\)

Theo đề: \(n_{O_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\)

\(\Rightarrow0,5x+\dfrac{2}{3}y=0,6\left(2\right)\)

\(\xrightarrow[\left(2\right)]{\left(1\right)}\left\{{}\begin{matrix}24x+56y=36\\0,5x+\dfrac{2}{3}y=0,6\end{matrix}\right.\\ \Leftrightarrow\left\{{}\begin{matrix}x=0,8\\y=0,3\end{matrix}\right.\\ \Rightarrow\left\{{}\begin{matrix}m_{Mg}=0,8.24=19,2\left(g\right)\\m_{Fe}=0,3.56=16,8\left(g\right)\end{matrix}\right.\\ m_r=m_{MgO}+m_{Fe_3O_4}=0,8.40+\dfrac{1}{3}.0,3.232=55,2\left(g\right)\)

PTHH: 

mS=10−3,6=6,4(g)⇔nS=6,432=0,2(mol)mS=10−3,6=6,4(g)⇔nS=6,432=0,2(mol)

VO2=(0,3+0,2)22,4=11,2(l)VO2=(0,3+0,2)22,4=11,2(l)

mhh=mCO2+mSO2=0,3.44+0,2.64=26(g)

Đặt \(\left\{{}\begin{matrix}n_{Al}=x\left(mol\right)\\n_{Fe}=y\left(mol\right)\end{matrix}\right.\)

Theo đề: \(m_{hh}=39\left(g\right)\)

\(\Rightarrow m_{Al}+m_{Fe}=39\\ \Rightarrow27x+56y=39\left(1\right)\)

\(PTHH:4Al+3O_2\underrightarrow{t^o}2Al_2O_3\\ \left(mol\right)....x\rightarrow..0.75x....0,5x\\ PTHH:3Fe+2O_2\underrightarrow{t^o}Fe_3O_4\\ \left(mol\right)....y\rightarrow..\dfrac{2}{3}y.....\dfrac{1}{3}y\)

Theo đề: \(n_{O_2}=\dfrac{V}{22,4}=\dfrac{12,32}{22,4}=0,55\left(mol\right)\)

\(\Rightarrow0,75x+\dfrac{2}{3}y=0,55\left(2\right)\)

\(\xrightarrow[\left(1\right)]{\left(2\right)}\left\{{}\begin{matrix}27x+56y=39\\0,75x+\dfrac{2}{3}y=0,55\end{matrix}\right.\\ \Leftrightarrow\left\{{}\begin{matrix}x=0,2\\y=0,6\end{matrix}\right.\\ \Rightarrow\left\{{}\begin{matrix}m_{Al}=0,2.27=5,4\left(g\right)\\m_{Fe}=0,6.56=33,6\left(g\right)\end{matrix}\right.\\ m_r=m_{Al_2O_3}+m_{Fe_3O_4}=0,5.0,2.102+\dfrac{1}{3}.0,6.232=56,6\left(g\right)\)

nP = 3.1/31 = 0.1 (mol) 

4P + 5O2 -to-> 2P2O5 

0.1__0.125_____0.05

mP2O5 = 0.05*142 = 7.1 (g) 

VO2 = 0.125 * 22.4 = 2.8 (l)

Khối lượng thanh kim loại tăng lên = khối lượng Oxi

\(\Rightarrow m_O=9,6g\)

\(\Rightarrow n_O=\dfrac{9,6}{16}=0,6\left(mol\right)\)

\(\Rightarrow n_{O_2}=\dfrac{1}{2}n_O=0,3mol\)

\(\Rightarrow V_{O_2}=0,3.22,4=6,72l\)

Vậy chọn Đáp án D

a) PTHH : \(4Al+3O_2\underrightarrow{t^o}2Al_2O_3\).

b) Ta có : \(n_{Al_2O_3}=\dfrac{m_{Al_2O_3}}{M_{Al_2O_3}}=\dfrac{20,4}{102}=0,2\left(mol\right)\).

Theo phương trình, \(n_{Al}=2n_{Al_2O_3}=2.\left(0,2\right)=0,4\left(mol\right)\).

\(\Rightarrow m_{Al}=n_{Al}.M_{Al}=\left(0,4\right).27=10,8\left(g\right)\)

c) Theo phương trình và ý b) : \(n_{O_2}=\dfrac{3}{2}n_{Al_2O_3}=\dfrac{3}{2}\cdot0,2=0,3\left(mol\right)\).

\(\Rightarrow V_{O_2}=n_{O_2}.22,4=\left(0,3\right).\left(22,4\right)=6,72\left(l\right)\).

\(\Rightarrow V_{KK}=5V_{O_2}=5.\left(6,72\right)=33,6\left(l\right)\).

THAM KHẢO:

Gọi số mol Mg và Zn lần lượt là x, y

Ta có 24x + 65y=23.3

     40x + 81y=36.1

=) x=0.7

    y= 0.1

b)

c)

\(a,2Mg+O_2\rightarrow\left(t^o\right)2MgO\\ 2Zn+O_2\rightarrow\left(t^o\right)2ZnO\\ b,n_{O_2}=\dfrac{36,1-23,3}{32}=0,4\left(mol\right)\\ V_{O_2\left(\text{đ}ktc\right)}=0,4.22,4=8,96\left(l\right)\\ \text{Đ}\text{ặt}:a=n_{Mg};b=n_{Zn}\left(a,b>0\right)\left(mol\right)\\ \Rightarrow\left\{{}\begin{matrix}24a+65b=23,3\\0,5a+0,5b=0,4\end{matrix}\right.\Leftrightarrow\left\{{}\begin{matrix}a=0,7\\b=0,1\end{matrix}\right.\\ c,m_{Mg}=24a=24.0,7=16,8\left(g\right)\\ m_{Zn}=65b=65.0,1=6,5\left(g\right)\)

a) $n_{Al} = \dfrac{5,4}{27} = 0,2(mol)$
$4Al + 3O_2 \xrightarrow{t^o} 2Al_2O_3$

Theo PTHH : $n_{O_2} = \dfrac{3}{4}n_{Al} = 0,15(mol)$
$V_{O_2} = 0,15.22,4 = 3,36(lít)$

b) $2 KClO_3 \xrightarrow{t^o} 2KCl + 3O_2$

$n_{KClO_3} = \dfrac{2}{3}n_{O_2} = 0,1(mol)$
$m_{KClO_3} = 0,1.122,5 = 12,25(gam)$

\(n_{Al}=\dfrac{m}{M}=\dfrac{5,4}{27}=0,2\left(mol\right)\\ PTHH:4Al+3O_2-^{t^o}>2Al_2O_3\)

tỉ lệ:         4      :     3     :     2

n(mol)     0,2---->0,15---->0,1

\(V_{O_2\left(dktc\right)}=n\cdot22,4=0,15\cdot22,4=3,36\left(l\right)\\ PTHH:2KClO_3-^{t^o}>2KCl+3O_2\)

tỉ lệ:            2             :      2         :    3

n(mol)        0,1<-------------------------0,15

\(m_{KClO_3}=n\cdot M=0,1\cdot\left(39+35,5+16\cdot3\right)=12,25\left(g\right)\)

4Al+3O₂-to>2Al₂O₃

0,2---0,15------0,1 mol

n Al=0,2 mol

VO₂=0,15.22,4=3,36l

b) 2KClO₃-to>2KCl +3O₂

    0,1---------------------0,15 mol

->m KClO₃=0,1.122,5g

#yT

4Al+3O₂-to>2Al₂O₃

0,2--0,15--------0,1 mol

n Al=\(\dfrac{5,4}{27}\)=0,2 kmol

=>V_O2=0,15.22,4=3,36(kl)

=>m _Al2O3=0,1.102=10,2kg