a, \(n_{H^+}=0,025.0,2=0,005\left(mol\right)\)
\(n_{OH^-}=0,01.2.0,3=0,006\left(mol\right)\)
\(\Rightarrow n_{OH^-dư}=0,001\left(mol\right)\)
\(\Rightarrow\left[OH^-\right]_{dư}=\dfrac{0,001}{1}=10^{-3}\)
\(\Rightarrow\left[H^+\right]=10^{-11}\)
\(\Rightarrow pH=11\)
b, \(n_{Fe^{2+}}=n_{SO_4^{2-}}=0,02.0,1=0,002\left(mol\right)\)
\(n_{Ba^{2+}}=0,01.0,3=0,003\left(mol\right)\)
\(\Rightarrow\left\{{}\begin{matrix}n_{BaSO_4\downarrow}=n_{SO_4^{2-}}=0,002\left(mol\right)\\n_{Fe\left(OH\right)_2\downarrow}=n_{OH^-dư}=0,001\left(mol\right)\end{matrix}\right.\)
\(\Rightarrow m_{\downarrow}=0,002.233+0,001.90=0,556\left(g\right)\)