a) nCO2 = 0,1 mol
nCa(OH)2 = 0,1 mol
\(\dfrac{nCO2}{nCa\left(OH\right)2}=\dfrac{0,1}{0,1}=1\) => tạo ra muối CaCO3
CO2 (0,1) + Ca(OH)2 (0,1) -----> CaCO3 (0,1) + H2O
- Theo PTHH: nCaCO3 = 0,1 mol
=> mCaCO3 = 0,1 . 100 = 10 gam
b) nCO2 = 0,1 mol
nCa(OH)2 = 0,05 mol
\(\dfrac{nCO2}{nCa\left(OH\right)2}=\dfrac{0,1}{0,05}=2\) => tạo ra muối Ca(HCO3)2
2CO2 (0,1) + Ca(OH)2 (0,05) -----> Ca(HCO3)2 (0,05)
- Theo PTHH: nCa(HCO3)2 = 0,05 mol
=> mCa(HCO3)2 = 0,05 . 162 = 8,1 gam
c) nCO2 = 0,1 mol
nCa(OH)2 = 5/74 mol
\(\dfrac{nCO2}{nCa\left(OH\right)2}=\dfrac{0,1}{\dfrac{5}{74}}=1,48\) => tạo ra 2 muối Ca(HCO3)2 và CaCO3
- Đặt nCaCO3 = x mol và nCa(HCO3)2 = y mol
CO2 (x) + Ca(OH)2 (x) -----> CaCO3 (x) + H2O (1)
2CO2 (2y) + Ca(OH)2 (y) -----> Ca(HCO3)2 (y) (2)
- Theo PTHH (1,2): \(\left\{{}\begin{matrix}x+2y=0,1\\x+y=\dfrac{5}{74}\end{matrix}\right.\)
\(\Rightarrow\left\{{}\begin{matrix}x=\dfrac{13}{370}\left(mol\right)\\y=\dfrac{6}{185}\left(mol\right)\end{matrix}\right.\)
=> mCaCO3 = 13/370 . 100 = 130/37 (gam)
=> mCa(HCO3)2 = 6/185 . 162 = 972/185 (gam)