2KMnO4 \(\underrightarrow{t^o}\)K2MnO4 + MnO2 + O2 (1)
2KClO3 \(\underrightarrow{t^o}\)2KCl + 3O2 (2)
Đặt nKMnO4=a
nKClO3=b
Ta có:
\(\left\{{}\begin{matrix}158a+122,5b=56,1\\\dfrac{1}{2}a+\dfrac{3}{2}b=0,4\end{matrix}\right.\)
=>a=b=0,2
mKMnO4=158.0,2=31,6(g)
mKClO3=56,1-31,6=24,5(g)
b;Theo PTHH 1 ta có:
\(\dfrac{1}{2}n_{KMnO_4}=n_{K_2MnO_4}=n_{MnO_2}=0,1\left(mol\right)\)
\(\Rightarrow m_{K_2MnO_4}=0,1.197=19,7\left(g\right)\)
\(m_{MnO_2}=87.0,1=8,7\left(g\right)\)
Theo PTHH 2 ta có:
nKClO3=nKCl=0,2(mol)
mKCl=0,2.74,5=14,9(g)