a) 4P+5O2--->2P2O5
P2O5+4NaOH----->2 Na2HPO4+H2O
n\(_P=\frac{6,2}{32}=0,2\left(mol\right)\)
Theo pthh1
n\(_{P2O5}=\frac{1}{2}n_P=0,1\left(mol\right)\)
Theo pthh2
n\(_{NaOH}=4n_{P2O5}=0,4\left(mol\right)\)
mdd NaOH=\(\frac{0,4.40.100}{32}=50\left(g\right)\)
b) m dd sau pư=50+0,1.142=192(g)
Theo pthh
n\(_{Na2HPO4}=2n_{P2O5}=0,2\left(mol\right)\)
C%=\(\frac{0,2.142}{192}.100\%=14,79\%\%\)
\(\text{nP = 6,2 : 31 = 0,2 mol}\)
PTHH: 4P + 5O2 --t^o--> 2P2O5
.............0,2 ---------------------> 0,1 (mol)
P2O5 + 3H2O -> 2H3PO4
0,1 -----------------> 0,2 (mol)
H3PO4 + 2NaOH -> Na2HPO4 + 2H2O
0,2---------> 0,4 ----> 0,2.......................... (mol)
\(\text{a) mNaOH = 0,4.40 = 16 gam}\)
\(\Rightarrow\text{m dd NaOH = 16.(100/32) = 50 gam}\)
\(\text{b) m dd sau pư = mP2O5 + m dd NaOH = 0,1.142 + 50 = 64,2 gam}\)
\(\Rightarrow\text{C% Na2HPO4 =}\text{44,24%}\)