PTHH: 2Na + 2H2O -> 2NaOH+H2
Ta có:
nNa = 9,2/23 = 0,4 mol = nNaOH
=> mFe2(SO4)3 = 200.4% = 8 gam
=> nFe2(SO4)3 = 8/(56.2 + 96.3 )= 0,02 mol;
=> mAl2(SO4)3 = 6,84%.200 = 13,68 gam
=> nAl2(SO4)3 = 13,68/(27.2 + 96.3) = 0,04 mol
PTHH: Fe2(SO4)3 + 6NaOH -> 2Fe(OH)3 + 3Na2(SO4)3
Ta có:
nFe(OH)3 = 2nFe2(SO4)3 = 0,04 mol;
nNaOH còn lại = 0,2 − 0,02.6 = 0,08 mol
Al2(SO4)3 + 6NaOH -> 2Al(OH)3 + 3Na2SO4
nNaOH < 6nAl2(SO4)3 => nAl(OH)3 = 13nNaOH = 0,08/3
Nung kết tủa:
2Fe(OH)3 \(\underrightarrow{^{t^o}}\) Fe2O3 + 3H2O
2Al(OH)3 \(\underrightarrow{^{t^o}}\) Al2O3 + 3H2O
=> nFe2O3 = 1/2nFe(OH)3 = 0,02 mol
=> nAl2O3 = 1/2nAl(OH)3 = 0,04/3
=> mrắn = 0,02.160 + 0,04/3.(27.2 + 16.3) = 4,56 gam