a)
Gọi : \(\left\{{}\begin{matrix}n_{NaCl}=a\left(mol\right)\\n_{KI}=b\left(mol\right)\end{matrix}\right.\)
NaCl + AgNO3 → AgCl + NaNO3
a..............a...............a..............................(mol)
KI + AgNO3→ AgI + KNO3
b.......b..............b..................................(mol)
Ta có :
\(n_{AgNO_3} = a + b = 0,25.2 = 0,5(mol)\)
\(m_{kết\ tủa} = 143,5a + 235b = 103,775\)(gam)
Suy ra : a = 0,15 ; b = 0,35
Vậy :
\(C_{M_{NaCl}} = \dfrac{0,15}{0,4} = 0,375M\\ C_{M_{KI}} = \dfrac{0,35}{0,4} = 0,875M\)
b)
Sau phản ứng, dung dịch gồm : \(\left\{{}\begin{matrix}NaNO_3:0,15\left(mol\right)\\KNO_3:0,35\left(mol\right)\end{matrix}\right.\)
Suy ra :
\(m_{NaNO_3} = 0,15.85 = 12,75(gam)\\ m_{KNO_3} = 0,35.101 = 35,35(gam)\)