\(AlCl_3+3NaOH-->3NaCl+Al\left(OH\right)_3\left(1\right)\)
0,3________0,9____________0,9____0,3
\(FeCl_3+3NaOH-->3NaCl+Fe\left(OH\right)_3\left(2\right)\)
0,3_________0,9___________0,9______0,3
\(2Al\left(OH\right)_3--to->Al_2O_3+3H_2O\left(3\right)\)
(0,3-a)___________________(0,3-a)/2
\(2Fe\left(OH\right)_3--to->Fe_2O_3+3H_2O\left(4\right)\)
0,3________________0,15
=> Σ mchất rắn sau pứ=0,15.102+0,15.160=39,2>34,2
=> Al(OH)3 bj tan 1 phần
Đặt a là số mol Al(OH)3 tan
\(NaOH+Al\left(OH\right)_3-->NaAlO_2+2H_2O\left(5\right)\)
0,1__________0,1__________0,1
=> \(\dfrac{0,3-a}{2}.102+0,15.160=34,2\)
=>a=0,1
=>ΣnNaOH(pứ)=0,9+0,9+0,1=1,9(mol)
=>VNaOH=1,9(M)
D2B : NaCl,NaAlO2
=> ΣnNaCl=0,9+0,9=1,8(mol)
=>CM(NaCl)=1,8(M)
=>CM(NaAlO2)=0,1(M)