2Al + 6HCl \(\rightarrow\)2AlCl3 + 3H2 (1)
ZnO + 2HCl \(\rightarrow\)ZnCl2 + H2O (2)
nH2=\(\dfrac{13,44}{22,4}=0,6\left(mol\right)\)
Theo PTHH 1 ta có:
\(\dfrac{2}{3}\)nH2=nAl=0,4(mol)
mAl=0,4.27=10,8(g)
%mAl=\(\dfrac{10,8}{27}.100\%=40\%\)
%mZnO=100-40=60%
b;mZnO=27-10,8=16,2(g)
nZnO=\(\dfrac{16,2}{81}=0,2\left(mol\right)\)
Theo PTHH 1 và 2 ta có:
3nAl=nHCl(1)=1,2(mol)
2nZnO=nHCl(2)=0,4(mol)
mHCl=36,5.(0,4+1,2)=58,4(g)
mdd HCl=\(58,4:\dfrac{29,2}{100}=200\left(g\right)\)
c;
Theo PTHH 1 và 2 ta có:
nAl=nAlCl3=0,4(mol)
mAlCl3=0,4.133,5=53,4(g)
nZn=nZnCl2=0,2(mol)
mZnCl2=0,2.136=27,2(g)
C% dd AlCl3=\(\dfrac{53,4}{27+200-0,6.2}.100\%=23,65\%\)
C% dd ZnCl2=\(\dfrac{27,2}{27+200-1,2}.100\%=12,04\%\)
\(n_{H_2}=\dfrac{13,44}{22,4}=0,6\left(mol\right)\)
2Al + 6HCl \(\rightarrow\) 2AlCl3 + 3H2
de: 0,4 \(\leftarrow\) 1,2 \(\leftarrow\) 0,4 \(\leftarrow\) 0,6
\(m_{Al}=0,4.27=10,8g\)
\(m_{ZnO}=27-10,8=16,2g\)
\(n_{ZnO}=\dfrac{16,2}{81}=0,2\left(mol\right)\)
a, \(\%m_{Al}=\dfrac{10,8}{27}.100\%=40\%\)
\(\%m_{ZnO}=100-40=60\%\)
ZnO + 2HCl \(\rightarrow\) ZnCl2 + H2O
de: 0,2 \(\rightarrow\) 0,4 \(\rightarrow\) 0,2
b, \(m_{HCl}=36,5.\left(1,2+0,2\right)=51,1g\)
\(m_{ddHCl}=\dfrac{51,1}{29,2}.100=175g\)
c, \(m_{ZnCl_2}=0,2.136=27,2g\)
\(m_{AlCl_3}=0,4.133,5=53,4g\)
\(m_{dd}=175+27-0,6.2=200,8g\)
\(C\%_{ZnCl_2}=\dfrac{27,2}{200,8}.100\%\approx13,55\%\)
\(C\%_{AlCl_3}=\dfrac{53,4}{200,8}.100\%\approx26,59\%\)